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Scenarios for integration of bio-liquids in existing REFINERY processes

Deliverables

Training seminars

Two seminars organised for higher level university students using AspenPlus as a tool to evaluate and develop biomass co-refining. The seminars will be organised back to back with petroleum refining conferences such as Hydrocarbon processing or European Refining Technology Conference (ERTC).

Delivery of 300 kg of fractionated bio-liquid

The aim is to demonstrate the production of 300 kg of low water content pyrolysis bio-oil. Subsequently separation of lignin molecules from the sugars will be carried out using solvent extraction. Action of achieving this deliverable to be made Public. Related to task 2.1

Delivery of 300 kg of clean bio-liquid

The aim is to demonstrate the production of 300 kg of low ash pyrolysis bio-oil. Two days continuous operation of the fast fluidized-bed pilot operation is planned to accomplish this. Action of achieving this deliverable to be made Public. Related to Task 2.1

Final workshop

4REFINERY will organise a final workshop coinciding with the final project meeting in 2021 The workshop will be organised to engage with the relevant stakeholders to promote the results and exploitatoinRelated to task 61

Delivery of fuels obtained by Co-HDO and Co-HT

An analysis of the fuels obtained by Co-HDO (amounts and quality) and Co-HT: 50-100kg diesel of wide-ranging bio-content will be produced. Besides standard diesel properties, de-oxygenation efficiency of the Co-HT will be analysed. The results will be made available on demand on the 4Refinery web site and will be further integrated into the public white paper to be delivered at the end of the project Relatred to tasks 3.3 and 3.4

Delivery of 5-10 kg of HTL bio-liquid

The aim is to produce HTL bio-liquid according to the optimized settings as developed in the project. Approx 1 week of processing will be required for this. Related to task 2.2

Delivery of 1-3 L each of selected HTL bio-liquid fractions for upgrading

The aim is to provide HTL bio-liquid from the selected feedstocks for upgrading. Production campaigns will last 1-2 days for each feedstock and process setting. Related to task 2.2

Delivery of 200 kg of catalytic bio-liquid

The objective is to operate of the fast fluidized-bed pilot using pine sawdust as feedstock to produce about 200 kg of bio-liquid. The catalytic pyrolysis bio-liquid will serve as a reference to the thermal bio-liquids employed extensively within the project and will be the basis of further upgrading and refining within WP3. Action of achieving this deliverable to be made public. Related to task 2.1

Workshop on biofuel LCA

Organisation of a workshop on biofuel LCA AAU at the SETAC-LCA conference in 2018. The objective is to promote and present the project’s results and activities. Related to task 6.1

Delivery of 50-60 kg of HTL bio-liquid for baseline upgrading activities

The aim is to provide 50-60kg of high quality HTL bio-liquid for upgrading. Approx 2 full weeks of continuous operation of the CBS1 continuous pilot scale HTL facility is planned to accomplish this. Related to task 2.2

Conformation with H&S procedures

A letter that all participants will ensure that appropriate health and safety procedures conforming to relevant local/national guidelines/legislation are followed in order to avoid harming the staff involved in the project.

Public report on scenarios

This has the same goals as the previous deliverable. This will be a summary of D.1.7. Related to task 1.5

Report on public risk perception of biofuels

Report with guidance on dissemination of knowledge on biofuel production, based on screening of public risk perception and public acceptance of biofuels. Related to task 4.3

4REFINERY website

The 4REFINERY website will be developed to provide an overview of the objectives and programme of work, to track its progress and present relevant results of individual work packages. The website will be publicly accessible and will serve as a useful source of information for the RTD audience and other stakeholders. Relatead to task 6.1

Communication marketing material

Completion of a dissemination and communications strategy and visual identity of the 4REFINERY project. Includes logo posters and a project brochure that provides the wider audience with the key project messages. Related to task 6.1

Publications

Kinetics of n-Hexane Cracking over Mesoporous HY Zeolites Based on Catalyst Descriptors

Author(s): Yann Chapellière, Cécile Daniel, Alain Tuel, David Farrusseng, Yves Schuurman
Published in: Catalysts, Issue 11/6, 2021, Page(s) 652, ISSN 2073-4344
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/catal11060652

Co-Hydrothermal Liquefaction of Lignocellulosic Biomass in Supercritical Water

Author(s): Kamaldeep Sharma, Ayaz A. Shah, Saqib S. Toor, Tahir H. Seehar, Thomas H. Pedersen, Lasse A. Rosendahl
Published in: Energies, Issue 14/6, 2021, Page(s) 1708, ISSN 1996-1073
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/en14061708

Integration of hydrothermal liquefaction and carbon capture and storage for the production of advanced liquid biofuels with negative CO2 emissions

Author(s): E.M. Lozano, T.H. Pedersen, L.A. Rosendahl
Published in: Applied Energy, Issue 279, 2020, Page(s) 115753, ISSN 0306-2619
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.apenergy.2020.115753

Renewable hydrocarbon fuels from hydrothermal liquefaction: A techno-economic analysis

Author(s): Thomas Helmer Pedersen, Nick Høy Hansen, Oscar Miralles Pérez, Daniel Esteban Villamar Cabezas, Lasse A. Rosendahl
Published in: Biofuels, Bioproducts and Biorefining, Issue 12/2, 2018, Page(s) 213-223, ISSN 1932-104X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/bbb.1831

Continuous Hydrothermal Liquefaction of Biomass: A Critical Review

Author(s): Daniele Castello, Thomas Pedersen, Lasse Rosendahl
Published in: Energies, Issue 11/11, 2018, Page(s) 3165, ISSN 1996-1073
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/en11113165

Generic approach for the modeling of liquefied thermochemical products and biomass heat of formation. Case study: HTL biocrude, Pyrolysis oil and assessment of energy requirements

Author(s): Lozano, Eliana M.; Pedersen, Thomas H.; Rosendahl, Lasse
Published in: Applied Energy, Issue 2, 2019, ISSN 0306-2619
Publisher: Pergamon Press Ltd.

The role of catalysis in the valorization of woody biomass fast pyrolysis liquids: Overview and contribution of IRCELYON

Author(s): Nolven Guilhaume, Yves Schuurman, Christophe Geantet
Published in: Catalysis Today, Issue 373, 2021, Page(s) 5-23, ISSN 0920-5861
Publisher: Elsevier BV
DOI: 10.1016/j.cattod.2021.03.030

Modeling of thermochemically liquefied biomass products and heat of formation for process energy assessment

Author(s): E.M. Lozano, T.H. Pedersen, L.A. Rosendahl
Published in: Applied Energy, Issue 254, 2019, Page(s) 113654, ISSN 0306-2619
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.apenergy.2019.113654

Detailed Investigation of Compatibility of Hydrothermal Liquefaction Derived Biocrude Oil with Fossil Fuel for Corefining to Drop-in Biofuels through Structural and Compositional Analysis

Author(s): Kamaldeep Sharma, Thomas Helmer Pedersen, Saqib Sohail Toor, Yves Schuurman, Lasse Aistrup Rosendahl
Published in: ACS Sustainable Chemistry & Engineering, Issue 8/22, 2020, Page(s) 8111-8123, ISSN 2168-0485
Publisher: American Chemical Society
DOI: 10.1021/acssuschemeng.9b06253

Biofuels From 2G Biomass Liquefaction in Downstream Refinery Processes – 4REFINERY

Author(s): Duncan Akporiaye, Silje Fosse Håkonsen, Yves Schuurman
Published in: BE Sustainable Magazine, 2018
Publisher: ETA-Florence Renewable Energies

Boosting biomass liquefaction productivity and co-processing next generation biofuels in downstream refinery processes

Author(s): Kristin Onarheim
Published in: PyNe Newsletter, Issue 42, 2018, Page(s) 6, 13-14
Publisher: IEA Bioenergy

Integrating bio-liquids into existing refinery processes – The 4Refinery project

Author(s): Silje Fosse Håkonsen and Duncan Akporiaye
Published in: BE Sustainable Magazine, 2019
Publisher: ETA-Florence Renewable Energies

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