Calix[4]pyrrole for p-block elements: anti-van’t Hoff-Le Bel configuration and ligand-element cooperativity revive the standard oxidation states.

Project Information

pCx4All

Grant agreement ID: 948708

DOI 10.3030/948708

EC signature date 4 September 2020

Start date 1 November 2020

End date 31 October 2025

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 499 500,00

EU contribution € 1 499 500,00

Coordinated by

RUPRECHT-KARLS-UNIVERSITAET HEIDELBERG
Germany

Publications

Peer reviewed articles (12)

Valence Tautomerism of p-Block Element Compounds – An Eligible Phenomenon for Main Group Catalysis?

Author(s): Lutz Greb
Published in: European Journal of Inorganic Chemistry, 2021, ISSN 1099-0682
Publisher: John Wiley
DOI: 10.1002/ejic.202100871

Calix[4]pyrrolato gallate: square planar-coordinated gallium(<scp>iii</scp>) and its metal–ligand cooperative reactivity with CO₂ and alcohols

Author(s): Lukas M. Sigmund; Eliane Engels; Nick Richert; Lutz Greb
Published in: Chemical Science, Issue 1, 2022, ISSN 2041-6539
Publisher: RSC
DOI: 10.1039/d2sc03054c

Stereoinversion of Tetrahedral p-Block Element Hydrides

Author(s): Lukas Maximilian Sigmund, Christopher Ehlert, Ganna Gryn'ova, and Lutz Greb
Published in: The Journal of Chemical Physics, 2022, ISSN 0021-9606
Publisher: American Institute of Physics
DOI: 10.1063/5.0090267

Calix[4]pyrrolato Stibenium: Lewis Superacidity by Antimony(III)-Antimony(V) Electromerism

Author(s): Dr. Marcel Schorpp, Dr. Ravi Yadav, Daniel Roth, Prof. Dr. Lutz Greb
Published in: Angewandte Chemie International Edition, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202207963

Dioxygen Activation and Pyrrole α-Cleavage with Calix[4]pyrrolato Aluminates: Enzyme Model by Structural Constraint

Author(s): Lukas M. Sigmund; Christopher Ehlert; Markus Enders; Jürgen Graf; Ganna Gryn'ova; Ganna Gryn'ova; Lutz Greb
Published in: Angewandte Chemie International Edition, Issue 1, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202104916

The inversion of tetrahedral p-block element compounds: general trends and the relation to the second-order Jahn–Teller effect†

Author(s): Lukas M. Sigmund; Rouven Maier; Lutz Greb
Published in: Chemical Science, Issue 1, 2022, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc05395g

Trialkoxysilane Exchange: Scope, Mechanism, Cryptates and pH-Response

Author(s): Hollstein, Selina; Erdmann, Philipp; Ulmer, Andreas; Löw, Henrik; Greb, Lutz; von Delius, Max
Published in: Angewandte Chemie International Edition, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.5281/zenodo.8402403

Calix[4]pyrroles as ligands: recent progress with a focus on the emerging p-block element chemistry.

Author(s): Heiko Ruppert; Lukas M. Sigmund; Lutz Greb
Published in: Chemical Communications, Issue 1, 2021, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc05120b

Calix[4]pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers

Author(s): Dr. Florian Schön, Lukas M. Sigmund, Friederike Schneider, Dr. Deborah Hartmann, Matthew A. Wiebe, Prof. Ian Manners, Prof. Dr. Lutz Greb
Published in: Angewandte Chemie International Edition, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202202176

Calix[4]pyrrolato-germane-(thf)₂: Unlocking the Anti-van’t Hoff–Le Bel Reactivity of Germanium(IV) by Ligand Dissociation

Author(s): Ravi Yadav; Paul Janßen; Marcel Schorpp; Lutz Greb
Published in: Journal of the American Chemical Society, 2023, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c04424

Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal-Centered σ-Donor

Author(s): Heiko Ruppert, Lutz Greb
Published in: Angewandte Chemie International Edition, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202116615

An isolable, crystalline complex of square-planar silicon(IV)

Author(s): Fabian Ebner, Lutz Greb
Published in: Chem, 2021, ISSN 2451-9294
Publisher: Elsevier
DOI: 10.1016/j.chempr.2021.05.002