Circular Processing of Seawater Brines from Saltworks for Recovery of Valuable Raw Materials

Informacje na temat projektu

SEArcularMINE

Identyfikator umowy o grant: 869467

DOI 10.3030/869467

Projekt został zamknięty

Data podpisania przez KE 16 Kwietnia 2020

Data rozpoczęcia 1 Czerwca 2020

Data zakończenia 31 Sierpnia 2024

Finansowanie w ramach

• SOCIETAL CHALLENGES - Climate action, Environment, Resource Efficiency and Raw Materials

Koszt całkowity € 5 834 016,25

Wkład UE € 5 834 016,25

Koordynowany przez

UNIVERSITA DEGLI STUDI DI PALERMO
Italy

CORDIS oferuje możliwość skorzystania z odnośników do publicznie dostępnych publikacji i rezultatów projektów realizowanych w ramach programów ramowych HORYZONT.

Odnośniki do rezultatów i publikacji związanych z poszczególnymi projektami 7PR, a także odnośniki do niektórych konkretnych kategorii wyników, takich jak zbiory danych i oprogramowanie, są dynamicznie pobierane z systemu OpenAIRE .

Rezultaty

Websites, patent fillings, videos etc. (2)

Dissemination Resources and Tools 2

Updated portfolio of Dissemination Resources and Tools

Dissemination Resources and Tools 1

A report describing the portfolio of Dissemination Resources and Tools

Documents, reports (5)

LCA and LCC analysis

Life Cycle Assessment and Life Cycle Costing of the different processes

Pre- and post-concentration technologies

A report presenting the options to be used for pre and postconcentration of Li and TEsrich solutions

Brokerage event

Minutes of the Brokerage Event in Tunisia

SEArcularMINE Final Event

Minutes of the SEArcularMINE Final Event in Sicily

Lab-characterisation of Li and TEs crystallisation

A report presenting the results of laboratory experimental campaign for the characterisation of Li and TEs crystallisation options

Other (3)

TEs-pHSA model

A model for the analysis and design of the TEspHSA prototype

Mg-CGCR model

A model for the analysis and design of the MgCGCR prototype

Li-MFCDI model

A model for the analysis and design of the LiMFCDI prototype

Demonstrators, pilots, prototypes (1)

EDBM prototype

An EDBM unit adapted to operate under SEArcularMINE conditions and tested with artificial and real brines

Open Research Data Pilot (2)

Data Management Plan

A report describing the Data Management Plan to be implemented

Final Data Management Plan

A report presenting the Final Data Management Plan

Publikacje

Peer reviewed articles (24)

Selective recovery of boron, cobalt, gallium and germanium from seawater solar saltworks brines using N-methylglucamine sorbents: Column operation performance

Autorzy: V. Vallès, M. Fernández de Labastida, J. López, J.L. Cortina
Opublikowane w: Science of The Total Environment, Numer 923, 2024, Strona(/y) 171438, ISSN 0048-9697
Wydawca: Elsevier BV
DOI: 10.1016/j.scitotenv.2024.171438

The influence of flow electrode channel design on flow capacitive deionization performance: Experimental and CFD modelling insights

Autorzy: H.M. Saif, T.H. Gebregeorgis, J.G. Crespo, S. Pawlowski
Opublikowane w: Desalination, Numer 578, 2024, Strona(/y) 117452, ISSN 0011-9164
Wydawca: Elsevier BV
DOI: 10.1016/j.desal.2024.117452

Integrating diffusion dialysis for sustainable acid recovery from ion exchange regeneration stages: Characterization of metal and non-metal ions migration

Autorzy: V. Vallès, M. Fernández de Labastida, S. Randazzo, A. Cipollina, D. Winter, J. Koschikowski, J. López, J.L. Cortina
Opublikowane w: Separation and Purification Technology, Numer 353, 2024, Strona(/y) 128281, ISSN 1383-5866
Wydawca: Pergamon Press Ltd.
DOI: 10.1016/j.seppur.2024.128281

Development of highly selective composite polymeric membranes for Li+/Mg2+ separation

Autorzy: H.M. Saif; Rosa M. Huertas; Sylwin Pawlowski; João G. Crespo; Svetlozar Velizarov
Opublikowane w: Journal of Membrane Science, Numer Volume 620, 15 February 2021, 118891, 2020, ISSN 0376-7388
Wydawca: Elsevier BV
DOI: 10.1016/j.memsci.2020.118891

Describing ion transport and water splitting in an electrodialysis stack with bipolar membranes by a 2-D model: Experimental validation

Autorzy: T. León, J. López, R. Torres, J. Grau, L. Jofre, J.-L. Cortina
Opublikowane w: Journal of Membrane Science, Numer Volume 660, 2022, Strona(/y) 120835, ISSN 0376-7388
Wydawca: Elsevier BV
DOI: 10.1016/j.memsci.2022.120835

Lithium recovery from brines by lithium membrane flow capacitive deionization (Li-MFCDI) – A proof of concept

Autorzy: H.M. Saif; J.G. Crespo; S. Pawlowski
Opublikowane w: Journal of Membrane Science Letters, Numer Volume 3, Numer 2,, 2023, Strona(/y) 100059, ISSN 2772-4212
Wydawca: Elsevier B.V.
DOI: 10.1016/j.memlet.2023.100059

Electrodialysis with bipolar membranes for the generation of NaOH and HCl solutions from brines: an inter-laboratory evaluation of thin and ultrathin non-woven cloth-based ion-exchange membranes

Autorzy: Tamara León; Syed Abdullah Shah; Julio López; Andrea Culcasi; Lluis Jofre; Andrea Cipollina; José Luis Cortina; Alessandro Tamburini; Giorgio Micale
Opublikowane w: Membranes, Numer Volume 12; Numer 12, 2022, Strona(/y) 1204, ISSN 2077-0375
Wydawca: Molecular Diversity Preservation International
DOI: 10.3390/membranes12121204

Mg(OH)2 Recovery from Real Bitterns: a Proof of Concept at Pilot Scale

Autorzy: Battaglia, Giuseppe; Ventimiglia, Lorenzo; Viggiano, Francesco P.M.; Vassallo, Fabrizio; Cipollina, Andrea; Tamburini, Alessandro; Micale, Giorgio
Opublikowane w: Chemical Engineering Transactions, Numer Vol 105, 2023, Strona(/y) 1-6, ISSN 2283-9216
Wydawca: Italian Association of Chemical Engineering
DOI: 10.3303/CET23105001

Characterization of Mg(OH)2 powders produced from real saltworks bitterns at a pilot scale

Autorzy: G. Battaglia, L. Ventimiglia, F. Vicari, A. Tamburini, A. Cipollina, G. Micale
Opublikowane w: Powder Technology, Numer 443, 2024, Strona(/y) 119918, ISSN 0032-5910
Wydawca: Elsevier BV
DOI: 10.1016/j.powtec.2024.119918

Sustainable recovery of critical elements from seawater saltworks bitterns by integration of high selective sorbents and reactive precipitation and crystallisation: Developing the probe of concept with on-site produced chemicals and energy

Autorzy: V. Vallès, M. Fernández de Labastida, J. López, G. Battaglia, D. Winter, S. Randazzo, A. Cipollina, J.L. Cortina
Opublikowane w: Separation and Purification Technology, Numer Volume 306, Part B, 2023, Strona(/y) 122622, ISSN 1383-5866
Wydawca: Pergamon Press Ltd.
DOI: 10.1016/j.seppur.2022.122622

Boosting sustainable water production by upstream integration of desalination with saltworks in the Mediterranean region

Autorzy: A. Campione, M. Salem, S. Chamam, F. Vicari, R. Cucchiara, A. Hannachi, D. Pastorelli, A. Cipollina
Opublikowane w: Desalination and Water Treatment, Numer 317, 2024, Strona(/y) 100134, ISSN 1944-3986
Wydawca: Desalination and Water Treatment
DOI: 10.1016/j.dwt.2024.100134

Recovery of Lithium Carbonate from Dilute Li-Rich Brine via Homogenous and Heterogeneous Precipitation

Autorzy: Giuseppe Battaglia, Leon Berkemeyer, Andrea Cipollina, José Luis Cortina, Marc Fernandez de Labastida, Julio Lopez Rodriguez, and Daniel Winter
Opublikowane w: Ind. Eng. Chem. Res, Numer 2022, 61,36, 2022, Strona(/y) 13589-13602, ISSN 0888-5885
Wydawca: American Chemical Society
DOI: 10.1021/acs.iecr.2c01397

Evaluation of the purity of magnesium hydroxide recovered from saltwork bitterns

Autorzy: Giuseppe Battaglia; Maria Alda Domina; Rita Lo Brutto; Julio Lopez Rodriguez; Marc Fernandez de Labastida; Jose Luis Cortina; Alberto Pettignano; Andrea Cipollina; Alessandro Tamburini; Giorgio Micale
Opublikowane w: Water, Numer 4, 2023, Strona(/y) 29, ISSN 2073-4441
Wydawca: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/w15010029

Computational Modeling of Magnesium Hydroxide Precipitation and Kinetics Parameters Identification

Autorzy: Antonello Raponi, Salvatore Romano, Giuseppe Battaglia, Antonio Buffo, Marco Vanni, Andrea Cipollina, Daniele Marchisio
Opublikowane w: Crystal Growth & Design, Numer 23, 2023, Strona(/y) 4748-4759, ISSN 1528-7483
Wydawca: American Chemical Society
DOI: 10.1021/acs.cgd.2c01179

In-depth insights on multi-ionic transport in Electrodialysis with bipolar membrane systems

Autorzy: Antonia Filingeri, Julio Lopez, Andrea Culcasi, Tamara Leon, Alessandro Tamburini, José Luis Cortina, Giorgio Micale, Andrea Cipollina
Opublikowane w: Chemical Engineering Journal, Numer 468, 2024, Strona(/y) 143673, ISSN 1385-8947
Wydawca: Elsevier BV
DOI: 10.1016/j.cej.2023.143673

An Experimental Investigation of Electrodialysis with Bipolar Membranes Long-Run Performances with Real Solutions from Saltworks

Autorzy: Antonia Filingeri, Andrea Culcasi, Sarah Mueller, Julio Lopez, Alessandro Tamburini, Christian Linnartz, José Luis Cortina, Andrea Cipollina, Giorgio Micale
Opublikowane w: Chemical Engineering Transactions, Numer Volume 105, 2023, Strona(/y) 535, ISSN 2283-9216
Wydawca: Italian Association of Chemical Engineering
DOI: 10.3303/cet23105090

Unlocking hidden mineral resources: Characterization and potential of bitterns as alternative sources of critical raw materials

Autorzy: S. Randazzo, F. Vicari, J. López, M. Salem, R. Lo Brutto, S. Azzouz, S. Chamam, S. Cataldo, N. Muratore, M. Fernández de Labastida, V. Vallès, A. Pettignano, G. D’Alì Staiti, S. Pawlowski, A. Hannachi, J.L. Cortina, A. Cipollina
Opublikowane w: Journal of Cleaner Production, Numer 436, 2024, Strona(/y) 140412, ISSN 0959-6526
Wydawca: Elsevier BV
DOI: 10.1016/j.jclepro.2023.140412

Analysis of particles size distributions in Mg(OH)2 precipitation from highly concentrated MgCl2 solutions

Autorzy: G.Battaglia, S.Romano, A.Raponi, D.Marchisio, M.Ciofalo, A.Tamburini, A.Cipollina, G.Micale
Opublikowane w: Powder Technology, Numer Volume 398, 2022, ISSN 0032-5910
Wydawca: Elsevier BV
DOI: 10.1016/j.powtec.2021.117106

Polymeric and inorganic sorbents as a green option to recover critical raw materials at trace levels from sea saltwork bitterns

Autorzy: V. Vallès, J. López, M. Fernández de Labastida, O. Gibert, A. Leskinen, R. T. Koivula and J. L. Cortina
Opublikowane w: Green Chemistry, Numer 25, 2023, Strona(/y) 700-719, ISSN 1463-9270
Wydawca: The Royal Society of Chemistry
DOI: 10.1039/d2gc02338e

The Role of Operating Conditions in the Precipitation of Magnesium Hydroxide Hexagonal Platelets Using NaOH Solutions

Autorzy: Salvatore Romano, Silvio Trespi, Ramona Achermann, Giuseppe Battaglia, Antonello Raponi, Daniele Marchisio, Marco Mazzotti, Giorgio Micale, Andrea Cipollina
Opublikowane w: Crystal Growth & Design, Numer 23, 2023, Strona(/y) 6491-6505, ISSN 1528-7483
Wydawca: American Chemical Society
DOI: 10.1021/acs.cgd.3c00462

Population balance modelling of magnesium hydroxide precipitation: Full validation on different reactor configurations

Autorzy: Antonello Raponi, Ramona Achermann, Salvatore Romano, Silvio Trespi, Marco Mazzotti, Andrea Cipollina, Antonio Buffo, Marco Vanni, Daniele Marchisio
Opublikowane w: Chemical Engineering Journal, Numer 477, 2024, Strona(/y) 146540, ISSN 1385-8947
Wydawca: Elsevier BV
DOI: 10.1016/j.cej.2023.146540

Mixing phenomena in circular and rectangular cross-sectional T-mixers: Experimental and numerical assessment

Autorzy: G. Battaglia, S. Romano, A. Raponi, F. Volpe, L. Bellanca, M. Ciofalo, D. Marchisio, A. Cipollina, G. Micale, A. Tamburini
Opublikowane w: Chemical Engineering Research and Design, Numer 201, 2024, Strona(/y) 228-241, ISSN 0263-8762
Wydawca: Institute of Chemical Engineers
DOI: 10.1016/j.cherd.2023.11.056

Energetic Valorisation of Saltworks Bitterns via Reverse Electrodialysis: A Laboratory Experimental Campaign

Autorzy: Syed Abdullah Shah; Roberta Cucchiara; Fabrizio Vicari; Andrea Cipollina; Alessandro Tamburini; Giorgio Micale
Opublikowane w: Membranes, Numer 13(3), 2023, Strona(/y) 293, ISSN 2077-0375
Wydawca: Molecular Diversity Preservation International
DOI: 10.3390/membranes13030293

Mining minerals and critical raw materials from bittern: Understanding metal ions fate in saltwork ponds

Autorzy: Vicari, F; Randazzo, S; López, J; Fernández de Labastida, M; Vallès, V; Micale, G; Tamburini, A; D'Alì Staiti, G; Cortina, J L; Cipollina, A
Opublikowane w: Science of The Total Environment, Numer Volume 847, 2022, Strona(/y) 157544, ISSN 0048-9697
Wydawca: Elsevier BV
DOI: 10.1016/j.scitotenv.2022.157544

Conference proceedings (2)

Magnesium hydroxide nanoparticles production from natural bitterns.

Autorzy: Battaglia, Giuseppe Domina, Maria Alda Romano, Salvatore Tamburini, Alessandro Cipollina, Andrea Micale, Giorgio
Opublikowane w: Chemical Engineering Transactions, Numer Vol 96 (2022), 2022, Strona(/y) 43-48, ISBN 978-88-95608-95-2
Wydawca: AIDIC Servizi S.r.l.
DOI: 10.3303/cet2296008

Experimental Assessment of the Mixing Quality in a Circular Cross-sectional T-shaped Mixer for the Precipitation of Sparingly Soluble Compounds

Autorzy: Romano S., Battaglia G., Bonafede S., Marchisio D., Ciofalo M., Tamburini A., Cipollina A., Micale G.
Opublikowane w: Chemical Engineering Transactions, Numer Vol 86 (2021), 2021, Strona(/y) 1165-1170, ISSN 2283-9216
Wydawca: AIDIC-Italian Association of Chemical Engineering
DOI: 10.3303/cet2186195

Prawa własności intelektualnej

Patent (2)

PROCEDURE FOR THE EXTRACTION OF MINERALS FROM SEA WATER, PLANT FOR EXTRACTION AND MINERALS OBTAINED THROUGH THE EXTRACTION PROCEDURE

Numer wniosku/publikacji: 20 189069
Data: 2020-08-01

PROCEDURE FOR THE EXTRACTION OF MINERALS FROM SEA WATER, PLANT FOR EXTRACTION AND MINERALS OBTAINED THROUGH THE EXTRACTION PROCEDURE

Numer wniosku/publikacji: 20 189069
Data: 2020-08-01
Wnioskodawca/wnioskodawcy: RESOURSEAS SRL