Innovative Manufacturing Routes for Next Generation Batteries in Europe

Livrables

Assessment of the State-of-the-Art of mult-physics modeling of gel-based and all-solid-state Li-Ion batteries

The state-of-the-art on multi-physics modeling of electrochemical energy storage systems will be assessed and the resulting document will be shared with the consortium. Both gel-based and all-solid-state Li-Ion technologies will be considered.

Evaluation of generic processes for ceramic and composites

The main objective is to evaluate the generic processes developed previously and adapt them for as broad use as possible. The promising electrolyte candidates identified in WP7 will be ranked in terms of processability, costs and upscale production, always considering their physicochemical and electrochemical properties.

Environmental assessment

A prospective life cycle assessment LCA will be conducted by the VUB The full LCA will identify the key performance indicators for the environmental impact including climate change energy efficiency resource depletion toxicity during mining water footprint land usage and external cost calculation Furthermore the environmental impacts will be complemented with social impacts to highlight the excellence on sustainability

Study on the impact of future cell technologies on module and pack concept

The goal is to evaluate the implication of ASSB properties on module and pack concepts One of the most significant property with a very high potential impact is the operating temperature which is usually higher than in the stateoftheart Li ion technologies

Roadmap for competitive production of all-solid batteries including considerations of other emerging technologies

The roadmap will provide an overall vision of potential processes within the different stages of manufacturing and the impact they could provide in terms of cost quality performance safety and lifetime Special emphasis will be given to the applicability of the manufacturing solutions to the several emerging battery technology possibilities and the identification of potential breakthroughs related to production Furthermore the potential benefits and future markets of novel production Technologies will be identified and evaluated

Document with final Cell Requirement and Specification for Automotive and Stationary Application

The top-level Li-ion cell specifications and requirements will be broken down from the requirements for an automotive and a stationary battery-system to provide a real industrial guideline. BMW is responsible for the automotive requirements and VARTA Storage for the stationary requirements.

Project Website

VMB will develop and maintain a project website and corporative image including logo flyer rollups in order to create a project identity increase the awareness of IMAGE and provide the interested public with information concerning the project itself and other relevant topics and events

Publications

Rapid Low-Dimensional Li + Ion Hopping Processes in Synthetic Hectorite-Type Li 0.5 [Mg 2.5 Li 0.5 ]Si 4 O 10 F 2

Auteurs: Caroline Hiebl, Patrick Loch, Marina Brinek, Maria Gombotz, Bernhard Gadermaier, Paul Heitjans, Josef Breu, H. Martin. R. Wilkening
Publié dans: Chemistry of Materials, Numéro 32/17, 2020, Page(s) 7445-7457, ISSN 0897-4756
Éditeur: American Chemical Society
DOI: 10.1021/acs.chemmater.0c02460

Fuzzy logic: about the origins of fast ion dynamics in crystalline solids

Auteurs: M. Gombotz, K. Hogrefe, R. Zettl, B. Gadermaier, H. Martin. R. Wilkening
Publié dans: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Numéro 379/2211, 2021, ISSN 1364-503X
Éditeur: Royal Society of London
DOI: 10.1098/rsta.2020.0434

The Electronic Conductivity of Single Crystalline Ga‐Stabilized Cubic Li 7 La 3 Zr 2 O 12 : A Technologically Relevant Parameter for All‐Solid‐State Batteries

Auteurs: Martin Philipp, Bernhard Gadermaier, Patrick Posch, Ilie Hanzu, Steffen Ganschow, Martin Meven, Daniel Rettenwander, Günther J. Redhammer, H. Martin R. Wilkening
Publié dans: Advanced Materials Interfaces, Numéro 7/16, 2020, Page(s) 2000450, ISSN 2196-7350
Éditeur: John Wiley & Sons
DOI: 10.1002/admi.202000450

Structural Disorder in Li 6 PS 5 I Speeds 7 Li Nuclear Spin Recovery and Slows Down 31 P Relaxation–Implications for Translational and Rotational Jumps as Seen by Nuclear Magnetic Resonance

Auteurs: M. Brinek, C. Hiebl, K. Hogrefe, I. Hanghofer, H. M. R. Wilkening
Publié dans: The Journal of Physical Chemistry C, Numéro 124/42, 2020, Page(s) 22934-22940, ISSN 1932-7447
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpcc.0c06090

Conductor–Insulator Interfaces in Solid Electrolytes: A Design Strategy to Enhance Li-Ion Dynamics in Nanoconfined LiBH 4 /Al 2 O 3

Auteurs: Roman Zettl, Katharina Hogrefe, Bernhard Gadermaier, Ilie Hanzu, Peter Ngene, Petra E. de Jongh, H. Martin R. Wilkening
Publié dans: The Journal of Physical Chemistry C, Numéro 125/27, 2021, Page(s) 15052-15060, ISSN 1932-7447
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpcc.1c03789

Improvement of Lithium Metal Polymer Batteries through a Small Dose of Fluorinated Salt

Auteurs: Alexander Santiago, Xabier Judez, Julen Castillo, Iñigo Garbayo, Amaia Sáenz de Buruaga, Lixin Qiao, Giorgio Baraldi, José Antonio Coca-Clemente, Michel Armand, Chunmei Li, Heng Zhang
Publié dans: The Journal of Physical Chemistry Letters, Numéro 11/15, 2020, Page(s) 6133-6138, ISSN 1948-7185
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpclett.0c01883

Lithium solid-state batteries: State-of-the-art and challenges for materials, interfaces and processing

Auteurs: Nicola Boaretto, Iñigo Garbayo, Sona Valiyaveettil Sobhanraj, Amaia Quintela, Chunmei Li, Montse Casas-Cabanas, Frederic Aguesse
Publié dans: Journal of Power Sources, Numéro 502, 2021, Page(s) 229919, ISSN 0378-7753
Éditeur: Elsevier BV
DOI: 10.1016/j.jpowsour.2021.229919

Production of high-energy Li-ion batteries comprising silicon-containing anodes and insertion-type cathodes

Auteurs: Gebrekidan Gebresilassie Eshetu, Heng Zhang, Xabier Judez, Henry Adenusi, Michel Armand, Stefano Passerini and Egbert Figgemeier
Publié dans: Nature Communications, Numéro 5459/12, 2021, ISSN 2041-1723
Éditeur: Nature Publishing Group
DOI: 10.1038/s41467-021-25334-8

Realizing a high-performance LiNi 0.6 Mn 0.2 Co 0.2 O 2 /silicon–graphite full lithium ion battery cell via a designer electrolyte additive

Auteurs: Felix Aupperle, Gebrekidan Gebresilassie Eshetu, Kevin W. Eberman, Ang Xioa, Jean-Sebastien Bridel, Egbert Figgemeier
Publié dans: Journal of Materials Chemistry A, Numéro 8/37, 2020, Page(s) 19573-19587, ISSN 2050-7488
Éditeur: Royal Society of Chemistry
DOI: 10.1039/d0ta05827k

High Li+ and Na+ Conductivity in New Hybrid Solid Electrolytes based on the Porous MIL-121 Metal Organic Framework

Auteurs: Roman Zettl, Sarah Lunghammer, Bernhard Gadermaier, Athmane Boulaoued, Patrik Johansson,H. Martin R. Wilkening, Ilie Hanzu
Publié dans: Advanced Energy Materials, Numéro 11/16, 2021, Page(s) 2003542, ISSN 1614-6832
Éditeur: Wiley-VCH Verlag
DOI: 10.1002/aenm.202003542

Suppressed Mobility of Negative Charges in Polymer Electrolytes with an Ether‐Functionalized Anion

Auteurs: Heng Zhang, Fangfang Chen, Oier Lakuntza, Uxue Oteo, Lixin Qiao, Maria Martinez‐Ibañez, Haijin Zhu, Javier Carrasco, Maria Forsyth, Michel Armand
Publié dans: Angewandte Chemie, Numéro 131/35, 2019, Page(s) 12198-12203, ISSN 0044-8249
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201905794

Importance of Composite Electrolyte Processing to Improve the Kinetics and Energy Density of Li Metal Solid-State Batteries

Auteurs: Jakub Zagórski, Begoña Silván, Damien Saurel, Frédéric Aguesse, Anna Llordés
Publié dans: ACS Applied Energy Materials, Numéro 3/9, 2020, Page(s) 8344-8355, ISSN 2574-0962
Éditeur: American Chemical Society
DOI: 10.1021/acsaem.0c00935

Lowering the Interfacial Resistance in Li6.4La3Zr1.4Ta0.6O12|Poly(Ethylene Oxide) Composite Electrolytes

Auteurs: Eveline Kuhnert, Lukas Ladenstein, Anna Jodlbauer, Christian Slugovc, Gregor Trimmel, H. Martin R. Wilkening, Daniel Rettenwander
Publié dans: Cell Reports Physical Science, Numéro 1/10, 2020, Page(s) 100214, ISSN 2666-3864
Éditeur: Elsevier
DOI: 10.1016/j.xcrp.2020.100214

Fast Li Ion Dynamics in the Mechanosynthesized Nanostructured Form of the Solid Electrolyte Li 3 YBr 6

Auteurs: Maria Gombotz, H. Martin R. Wilkening
Publié dans: ACS Sustainable Chemistry & Engineering, Numéro 9/2, 2021, Page(s) 743-755, ISSN 2168-0485
Éditeur: American Chemical Society
DOI: 10.1021/acssuschemeng.0c06694

Lithium ion dynamics in LiZr 2 (PO 4 ) 3 and Li 1.4 Ca 0.2 Zr 1.8 (PO 4 ) 3

Auteurs: Isabel Hanghofer, Bernhard Gadermaier, Alexandra Wilkening, Daniel Rettenwander, H. Martin R. Wilkening
Publié dans: Dalton Transactions, 2019, ISSN 1477-9226
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9dt01786k

Fast Rotational Dynamics in Argyrodite-Type Li 6 PS 5 X (X: Cl, Br, I) as Seen by 31 P Nuclear Magnetic Relaxation—On Cation–Anion Coupled Transport in Thiophosphates

Auteurs: Isabel Hanghofer, Bernhard Gadermaier, H. Martin R. Wilkening
Publié dans: Chemistry of Materials, 2019, ISSN 0897-4756
Éditeur: American Chemical Society
DOI: 10.1021/acs.chemmater.9b01435

Understanding the Origin of Enhanced Li-Ion Transport in Nanocrystalline Argyrodite-Type Li 6 PS 5 I

Auteurs: Marina Brinek, Caroline Hiebl, H. Martin R. Wilkening
Publié dans: Chemistry of Materials, Numéro 32/11, 2020, Page(s) 4754-4766, ISSN 0897-4756
Éditeur: American Chemical Society
DOI: 10.1021/acs.chemmater.0c01367

In Situ Optical Investigations of Lithium Depositions on Pristine and Aged Lithium Metal Electrodes

Auteurs: Hannes Kühnle, Edwin Knobbe and Egbert Figgemeier
Publié dans: Journal of The Electrochemical Society, Numéro 168, 2021, Page(s) 020510, ISSN 0013-4651
Éditeur: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/abdeeb

Direct Assessment of Ultralow Li+ Jump Rates in Single Crystalline Li3N by Evolution-Time-Resolved 7Li Spin-Alignment Echo NMR

Auteurs: Bernhard Gadermaier, Katharina Hogrefe, Prof. Dr. Paul Heitjans, Prof. Dr. H. Martin R. Wilkening
Publié dans: European Journal of Inorganic Chemistry, 2021, Page(s) 1028-1033, ISSN 1434-1948
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202000941

Anomalies in Bulk Ion Transport in the Solid Solutions of Li 7 La 3 M 2 O 12 (M = Hf, Sn) and Li 5 La 3 Ta 2 O 12

Auteurs: Lukas Ladenstein, Sanja Simic, Gerald Kothleitner, Daniel Rettenwander, H. Martin R. Wilkening
Publié dans: The Journal of Physical Chemistry C, Numéro 124/31, 2020, Page(s) 16796-16805, ISSN 1932-7447
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpcc.0c03558

Ion dynamics in Al-Stabilized Li7La3Zr2O12 single crystals – Macroscopic transport and the elementary steps of ion hopping

Auteurs: Patrick Posch, Sarah Lunghammer, Stefan Berendts, Steffen Ganschow, Günther J. Redhammer, Alexandra Wilkening, Martin Lerch, Bernhard Gadermaier, Daniel Rettenwander, H. Martin R. Wilkening
Publié dans: Energy Storage Materials, Numéro 24, 2020, Page(s) 220-228, ISSN 2405-8297
Éditeur: Elsevier
DOI: 10.1016/j.ensm.2019.08.017

With a Little Help from 31 P NMR: The Complete Picture on Localized and Long-Range Li + Diffusion in Li 6 PS 5 I

Auteurs: Katharina Hogrefe, Isabel Hanghofer, H. Martin R. Wilkening
Publié dans: The Journal of Physical Chemistry C, Numéro 125/41, 2021, Page(s) 22457-22463, ISSN 1932-7447
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpcc.1c06242

Tracking Ions the Direct Way: Long-Range Li + Dynamics in the Thio-LISICON Family Li 4 MCh 4 (M = Sn, Ge; Ch = S, Se) as Probed by 7 Li NMR Relaxometry and 7 Li Spin-Alignment Echo NMR

Auteurs: Katharina Hogrefe, Nicolò Minafra, Wolfgang G. Zeier, H. Martin R. Wilkening
Publié dans: The Journal of Physical Chemistry C, Numéro 125/4, 2021, Page(s) 2306-2317, ISSN 1932-7447
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpcc.0c10224

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