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CAlcium Rechargeable BAttery Technology

Deliverables

Project Quality Plan

Will describe the protocols undertaken for management of the project Having written protocols enables assessing quality

Comprehensive report: materials synthesized and characterized and assessed performance

Final report on experimental results related to cathode materials

Communication and dissemination Plan

Description of planned communication actions and dissemination strategy

Comprehensive report: selected cathode materials and computed magnitudes

Final report on computational results related to cathode materials

Benchmarking of the Ca technology in terms of performance and sustainability

Benchmarking of the technology developed with respect to state-of-the art technologies

Literature review of Ca conducting electrolytes

Report of previous know how available in scientific publications

Comprehensive report on alternative electrolyte concepts

Final report on non conventional electrolyte research

Full report on electrolyte physico-chemical and electrochemical properties

Final report on electrolyte research

Public website

Web page with public information regarding the project Will be constantly updated throughout the project

Demonstrator cells manufactured

Demonstrator cells manufactured with optimized components and protocols

Open Summer School

Open Summer School in multivalent battery electrochemical storage

Data Management Plan

Protocols for data management and preservation

Publications

Enlisting Potential Cathode Materials for Rechargeable Ca Batteries

Author(s): Arturo Torres, José Luis Casals, M. Elena Arroyo-de Dompablo
Published in: Chemistry of Materials, Issue 33(7), 2021, Page(s) 2488–2497, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.0c04741

Appraisal of calcium ferrites as cathodes for calcium rechargeable batteries: DFT, synthesis, characterization and electrochemistry of Ca 4 Fe 9 O 17

Author(s): Ashley P. Black, Arturo Torres, Carlos Frontera, M. Rosa Palacín, M. Elena Arroyo-de Dompablo
Published in: Dalton Transactions, Issue 49/8, 2020, Page(s) 2671-2679, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt04688g

Steps Towards the Use of TiS2 Electrodes in Ca Batteries

Author(s): R. Verrelli, A. Black, R. Dugas, D. Tchitchekova, A. Ponrouch, M. R. Palacin
Published in: Journal of the Electrochemical Society, 2020, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/ab7a82

On the road toward calcium-based batteries

Author(s): A. Ponrouch, M.R. Palacin
Published in: Current Opinion in Electrochemistry, Issue 9, 2018, Page(s) 1-7, ISSN 2451-9103
Publisher: Elsevier
DOI: 10.1016/j.coelec.2018.02.001

DFT investigation of Ca mobility in reduced-perovskite and oxidized-marokite oxides

Author(s): A. Torres, F.J. Luque, J. Tortajada, M.E. Arroyo-de Dompablo
Published in: Energy Storage Materials, Issue 21, 2019, Page(s) 354-360, ISSN 2405-8297
Publisher: Amsterdam: Elsevier
DOI: 10.1016/j.ensm.2019.06.002

Evaluation of cobalt oxides for calcium battery cathode applications

Author(s): A. Torres, F. Bardé, M.E. Arroyo-de Dompablo
Published in: Solid State Ionics, Issue 340, 2019, Page(s) 115004, ISSN 0167-2738
Publisher: Elsevier BV
DOI: 10.1016/j.ssi.2019.115004

Analysis of Minerals as Electrode Materials for Ca-based Rechargeable Batteries

Author(s): A. Torres, F. J. Luque, J. Tortajada, M. E. Arroyo-de Dompablo
Published in: Scientific Reports, Issue 9/1, 2019, ISSN 2045-2322
Publisher: Nature Publishing Group
DOI: 10.1038/s41598-019-46002-4

Post-Li batteries: promises and challenges

Author(s): Alexandre Ponrouch, M. Rosa Palacín
Published in: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Issue 377/2152, 2019, Page(s) 20180297, ISSN 1364-503X
Publisher: Royal Society of London
DOI: 10.1098/rsta.2018.0297

On the Study of Ca and Mg Deintercalation from Ternary Tantalum Nitrides

Author(s): Roberta Verrelli, Ashley Philip Black, Carlos Frontera, Judith Oró-Solé, Maria Elena Arroyo-de Dompablo, Amparo Fuertes, M. Rosa Palacín
Published in: ACS Omega, Issue 4/5, 2019, Page(s) 8943-8952, ISSN 2470-1343
Publisher: American Chemical Society
DOI: 10.1021/acsomega.9b00770

Multivalent rechargeable batteries

Author(s): A. Ponrouch, J. Bitenc, R. Dominko, N. Lindahl, P. Johansson, M.R. Palacin
Published in: Energy Storage Materials, Issue 20, 2019, Page(s) 253-262, ISSN 2405-8297
Publisher: Elsevier BV
DOI: 10.1016/j.ensm.2019.04.012

Achievements, Challenges, and Prospects of Calcium Batteries

Author(s): M. Elena Arroyo-de Dompablo, Alexandre Ponrouch, Patrik Johansson, M. Rosa Palacín
Published in: Chemical Reviews, 2019, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.9b00339

Cation Solvation and Physico-Chemical Properties of Ca Battery Electrolytes

Author(s): Juan D. Forero-Saboya, Elena Marchante, Rafael Barros Neves de Araújo, Damien Monti, Patrik Johansson, Alexandre Ponrouch
Published in: The Journal of Physical Chemistry C, 2019, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.9b07308

Towards novel calcium battery electrolytes by efficient computational screening

Author(s): Rafael B. Araujo, Vigneshwaran Thangavel, Patrik Johansson
Published in: Energy Storage Materials, Issue 39, 2021, Page(s) 89-95, ISSN 2405-8297
Publisher: Amsterdam: Elsevier
DOI: 10.1016/j.ensm.2021.04.015

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