Extending the range of the glassy state: Exploring structure and property limits in metallic glasses

Project Information

ExtendGlass

Grant agreement ID: 695487

DOI 10.3030/695487

Project closed

EC signature date 26 May 2016

Start date 1 October 2016

End date 31 October 2023

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 2 434 090,00

EU contribution € 2 434 090,00

Coordinated by

THE CHANCELLOR MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE
United Kingdom

Publications

Peer reviewed articles (53)

Ultrahigh thermal stability and hardness of nano-mixed fcc-Al and amorphous phases for multicomponent Al-based alloys

Author(s): Y. Jin, A. Inoue, F. L. Kong, S. L. Zhu, F. Al-Marzouki, A. L. Greer
Published in: Journal of Alloys and Compounds, 2020, ISSN 0925-8388
Publisher: Elsevier BV

Metallic glasses

Author(s): A. L. Greer, M. B. Costa, O. S. Houghton
Published in: MRS Bulletin, 2023, ISSN 0883-7694
Publisher: Materials Research Society

Thermal rejuvenation of an aged Au-based metallic glass by fast scanning calorimetry

Author(s): C.M. Meylan; K. Georgarakis; A.L. Greer
Published in: Journal of Non-Crystalline Solids: X, Vol 11, Iss , Pp 100062- (2021), 2021, ISSN 2590-1591
Publisher: Elsevier
DOI: 10.1016/j.nocx.2021.100062

Synergistic enhancement of hydrogen interactions in palladium–silicon–gold metallic glass with multilayered graphene

Author(s): Baran Sarac; Yurii P. Ivanov; Barbara Putz; Tolga Karazehir; Christian Mitterer; A. Lindsay Greer; A. Sezai Sarac; Jürgen Eckert
Published in: Journal of Materials Chemistry A, Issue 1, 2023, ISSN 2050-7496
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3ta01734f

Plastic Zr-Al-Ni-Cu-Ag bulk glassy alloys containing quasicrystalline or -Zr plus -Zr phases

Author(s): C. Liu, A. Inoue, F. L. Kong, S. L. Zhu, E. Shalaan, A. Al-Ghmadi, A. L. Greer
Published in: Acta Materialia, 2022, ISSN 1359-6454
Publisher: Elsevier BV

Atomic diffusivities in amorphous and liquid Cu-Zr: Kirkendall effects and dependence on packing density

Author(s): S. V. Ketov, Yu. P. Ivanov, B. Putz, Z. Zhang, J. Eckert, A. L. Greer
Published in: Acta Materialia, 2021, ISSN 1359-6454
Publisher: Elsevier BV

Hydrogen storage performance of the multi-principal-component CoFeMnTiVZr alloy in electrochemical and gas–solid reactions

Author(s): Vladislav Yu. Zadorozhnyy; Vladislav Yu. Zadorozhnyy; A.L. Greer; Semen N. Klyamkin; Mikhail Zadorozhnyy; A. Sezai Sarac; Adit Sharma; Artem Korol; D. Semenov; Jürgen Eckert; Jürgen Eckert; Yurii Ivanov; Yurii Ivanov; Baran Sarac; Selin Gumrukcu; E. A. Berdonosova
Published in: RSC Advances, 2020, ISSN 2046-2069
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0ra04089d

Transition metal-based high entropy alloy microfiber electrodes: Corrosion behavior and hydrogen activity

Author(s): Vladislav Yu. Zadorozhnyy; Sergey Kaloshkin; Semen N. Klyamkin; A. Lindsay Greer; Florian Spieckermann; E. A. Berdonosova; Jürgen Eckert; Jürgen Eckert; Jürgen Eckert; Mikhail Serov; Yurii Ivanov; Yurii Ivanov; Baran Sarac; A. Sezai Sarac
Published in: Corrosion Science, Issue 3, 2021, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2021.109880

Effective electrocatalytic methanol oxidation of Pd-based metallic glass nanofilms

Author(s): Yurii Ivanov; Yurii Ivanov; Baran Sarac; A. Lindsay Greer; Jürgen Eckert; Jürgen Eckert; Tolga Karazehir; Barbara Putz; Barbara Putz; A. Sezai Sarac
Published in: Nanoscale, Issue 1, 2020, ISSN 2040-3372
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0nr06372j

Advanced ultra-light multifunctional metallic-glass wave springs

Author(s): N. T. Panagiotopoulos, K. Georgarakis, A. M. Jorge Jr, M. Aljerf, W. J. Botta, A. L. Greer, A. R. Yavari
Published in: Materials and Design, 2020, ISSN 0264-1275
Publisher: Elsevier BV

In situ correlation between metastable phase-transformation mechanism and kinetics in a metallic glass

Author(s): Orava, Jiri; Balachandran, Shanoob; Han, Xiaoliang; Shuleshova, Olga; Nurouzi, Ebrahim; Soldatov, Ivan; Oswald, Steffen; Gutowski, Olof; Ivashko, Oleh; Dippel, Ann-Christin; Zimmermann, Martin V; Ivanov, Yurii P; Greer, A Lindsay; Raabe, Dierk; Herbig, Michael; Kaban, Ivan
Published in: Nat. Commun., 2021, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-021-23028-9

A conflict of fineness and stability: Platinum- and palladium-based bulk metallic glasses for jewellery: Part II. Processing, tarnish resistance and future developments

Author(s): O. S. Houghton, A. L. Greer
Published in: Johnson Matthey Technology Review, 2021, ISSN 2056-5135
Publisher: Johnson Matthey

Surface-governed electrochemical hydrogenation in FeNi-based metallic glass

Author(s): Yurii Ivanov; Yurii Ivanov; Baran Sarac; A. Kvaratskheliya; Selin Gumrukcu; Mária Omastová; A. Sezai Sarac; Mikhail Zadorozhnyy; Sergey V. Ketov; A. Lindsay Greer; Tolga Karazehir; E. A. Berdonosova; Jürgen Eckert; Jürgen Eckert; Vladislav Yu. Zadorozhnyy; Vladislav Yu. Zadorozhnyy; Matej Mičušík
Published in: Journal of Power Sources, 2020, ISSN 0378-7753
Publisher: Elsevier BV
DOI: 10.1016/j.jpowsour.2020.228700

Long-range-diffusion-assisted but interface-controlled crystallization of a Mg-Ni-Mm glass below its glass-transition temperature

Author(s): Yu. P. Ivanov, V. O. Semin, Z. Lu, J. Jiang, A. L. Greer, D. V. Louzguine-Luzgin
Published in: Journal of Alloys and Compounds, 2022, ISSN 1873-4669
Publisher: Elsevier BV

Novel phase decomposition, good soft-magnetic and mechanical properties for high-entropy (Fe0.25Co0.25Ni0.25Cr0.125Mn0.125)100–B (x = 9–13) amorphous alloys

Author(s): Inoue Akihisa; C.C. Zhao; A.L. Greer; Fanli Kong; C.J. Chen; Zhang Jinyao; Fahad M. Al-Marzouki; Baolong Shen
Published in: Journal of Alloys and Compounds, 2023, ISSN 0925-8388
Publisher: Elsevier BV
DOI: 10.1016/j.jallcom.2020.155917

Icosahedral and dodecagonal quasicrystal alloys with plastic deformability

Author(s): Y. Jin, A. Inoue, F. L. Kong, S .L. Zhu, F. Al-Marzouki, A. L. Greer
Published in: Acta Materialia, 2020, ISSN 1359-6454
Publisher: Elsevier BV

Machine-learning improves understanding of glass formation in metallic systems

Author(s): Robert M. Forrest; A. Lindsay Greer
Published in: Digital Discovery, 2024, ISSN 2635-098X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2dd00026a

Enhanced Oxygen Evolution Reaction of Zr-Cu-Ni-Al Metallic Glass with an Oxide Layer in Alkaline Media

Author(s): Baran Sarac; Yurii P. Ivanov; Matej Micusik; Maria Omastova; A. Sezai Sarac; Andrey I. Bazlov; Vladislav Zadorozhnyy; A. Lindsay Greer; Jürgen Eckert
Published in: ACS Catalysis, 2020, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.2c02672

The effect of Ni or Co additions on the structure of Zr60Cu30Al10 bulk metallic glass revealed by high-energy synchrotron radiation

Author(s): M. E. Stiehler, N. T. Panagiotopoulos, D. S. Keeble, Yu. P. Ivanov, M. Menelaou, M. R. Jolly, A. L. Greer, K. Georgarakis
Published in: Materials Today Communications, 2022, ISSN 2352-4928
Publisher: Elsevier BV

Anelastic-like nature of the rejuvenation of metallic glasses by cryogenic thermal cycling

Author(s): Costa, Miguel B.; Londoño, Juan J.; Blatter, Andreas; Hariharan, Avinash; Gebert, Annett; Carpenter, Michael A.; Greer, A. Lindsay
Published in: Acta Materialia, 2022, ISSN 1359-6454
Publisher: Elsevier BV
DOI: 10.1016/j.actamat.2022.118551

Enhancement of Interfacial Hydrogen Interactions with Nanoporous Gold-Containing Metallic Glass

Author(s): Sylvain Dancette; A. Lindsay Greer; Tolga Karazehir; Barbara Putz; Barbara Putz; A. Sezai Sarac; Mária Omastová; Yurii Ivanov; Yurii Ivanov; Baran Sarac; Matej Mičušík; Jürgen Eckert; Jürgen Eckert; Jürgen Eckert
Published in: ACS Applied Materials & Interfaces, 2021, ISSN 1944-8252
Publisher: American Chemical Society
DOI: 10.1021/acsami.1c08560

Additive manufacturing of a martensitic Co–Cr–Mo alloy: Towards circumventing the strength–ductility trade-off

Author(s): S. Scudino; Yu.P. Ivanov; Chao Yang; Konda Gokuldoss Prashanth; Konda Gokuldoss Prashanth; Konda Gokuldoss Prashanth; A.L. Greer; Wen Zhang; R.T. Qu; Zhi Wang; D. Wang; Shengyang Tang; Jürgen Eckert; Jürgen Eckert
Published in: Additive Manufacturing, 2021, ISSN 2214-8604
Publisher: Elsevier BV
DOI: 10.1016/j.addma.2020.101725

Zr-rich Zr-Al-Ni-Ag metallic glass composites with high strength and plastic strain

Author(s): C. Liu, A. Inoue, F. L. Kong, S. L. Zhu, E. Shalaan, A. Al-Ghmadi, A. L. Greer
Published in: Journal of Alloys and Compounds, 2022, ISSN 0925-8388
Publisher: Elsevier BV

Evolutionary design of machine-learning-predicted bulk metallic glasses

Author(s): Forrest, Robert M; Greer, A Lindsay
Published in: Digital Discovery, 2023, ISSN 2635-098X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2dd00078d

Cryo-Casting for Controlled Decomposition of Cu–Zr–Al Bulk Metallic Glass into Nanomaterials: Implications for Design Optimization

Author(s): Sung Hwan Hong; Wilfried Schranz; Sergey V. Ketov; A. Lindsay Greer; Yurii Ivanov; Yurii Ivanov; Baran Sarac; Ki Buem Kim; Jürgen Eckert; Jürgen Eckert; Jürgen Eckert; Jeong Tae Kim; Jeong Tae Kim; Viktor Soprunyuk; Viktor Soprunyuk
Published in: ACS Applied Nano Materials, 2021, ISSN 2574-0970
Publisher: American Chemical Society
DOI: 10.1021/acsanm.1c01055

Metallic Glass Films with Nanostructured Periodic Density Fluctuations Supported on Si/SiO₂ as an Efficient Hydrogen Sorber

Author(s): A. Sezai Sarac; Tolga Karazehir; Barbara Putz; Barbara Putz; Jürgen Eckert; Jürgen Eckert; Yurii Ivanov; Yurii Ivanov; Baran Sarac; A. Lindsay Greer
Published in: Chemistry - A European Journal, 2020, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001596

Enthalpy of anelasticity and rejuvenation of metallic glasses

Author(s): Costa, Miguel B.; Greer, A. Lindsay
Published in: Acta Materialia, 2024, ISSN 1359-6454
Publisher: Elsevier BV
DOI: 10.1016/j.actamat.2023.119609

Extreme rejuvenation and softening in a bulk metallic glass

Author(s): J. Pan, Y. X. Wang, Q. Guo, D. Zhang, A. L. Greer, Y. Li
Published in: Nature Communications, Issue 9/1, 2018, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-018-02943-4

On cryothermal cycling as a method for inducing structural changes in metallic glasses

Author(s): Sergey V. Ketov, Artem S. Trifonov, Yurii P. Ivanov, Alexander Yu. Churyumov, Alexander V. Lubenchenko, Alexander A. Batrakov, Jing Jiang, Dmitri V. Louzguine-Luzgin, Jurgen Eckert, Jiri Orava, Alan Lindsay Greer
Published in: NPG Asia Materials, Issue 10/4, 2018, Page(s) 137-145, ISSN 1884-4049
Publisher: Nature Publishing Group
DOI: 10.1038/s41427-018-0019-4

Strain-hardening and suppression of shear-banding in rejuvenated bulk metallic glass

Author(s): J. Pan, Yu. P. Ivanov, W. H. Zhou, Y. Li, A. L. Greer
Published in: Nature, Issue 578/7796, 2020, Page(s) 559-562, ISSN 0028-0836
Publisher: Nature Publishing Group
DOI: 10.1038/s41586-020-2016-3

High-resolution transmission electron microscopy investigation of diffusion in metallic glass multilayer films

Author(s): S.V. Ketov, Yu P. Ivanov, D. Şopu, D.V. Louzguine-Luzgin, C. Suryanarayana, A.O. Rodin, T. Schöberl, A.L. Greer, J. Eckert
Published in: Materials Today Advances, Issue 1, 2019, Page(s) 100004, ISSN 2590-0498
Publisher: Elsevier
DOI: 10.1016/j.mtadv.2019.01.003

Novel Heating-Induced Reversion during Crystallization of Al-based Glassy Alloys

Author(s): F. F. Han, A. Inoue, Y. Han, F. L. Kong, S. L. Zhu, E. Shalaan, F. Al-Marzouki, A. L. Greer
Published in: Scientific Reports, Issue 7/1, 2017, ISSN 2045-2322
Publisher: Nature Publishing Group
DOI: 10.1038/srep46113

Energy storage oscillation of metallic glass induced by high-intensity elastic stimulation

Author(s): S. Sohrabi, M. X. Li, H. Y. Bai, J. Ma, W. H. Wang, A. L. Greer
Published in: Applied Physics Letters, Issue 116/8, 2020, Page(s) 081901, ISSN 0003-6951
Publisher: American Institute of Physics
DOI: 10.1063/1.5140208

Classical-nucleation-theory analysis of priming in chalcogenide phase-change memory

Author(s): Jiri Orava, A. Lindsay Greer
Published in: Acta Materialia, Issue 139, 2017, Page(s) 226-235, ISSN 1359-6454
Publisher: Elsevier BV
DOI: 10.1016/j.actamat.2017.08.013

The atomistic mechanism of fast relaxation processes in Cu65Zr35 glass

Author(s): P. Palomino Rico, D.G. Papageorgiou, A.L. Greer, G.A. Evangelakis
Published in: Acta Materialia, Issue 135, 2017, Page(s) 290-296, ISSN 1359-6454
Publisher: Elsevier BV
DOI: 10.1016/j.actamat.2017.06.028

Ultrahigh hydrogen-sorbing palladium metallic-glass nanostructures

Author(s): Baran Sarac, Yurii P. Ivanov, Tolga Karazehir, Marlene Mühlbacher, Baris Kaynak, A. Lindsay Greer, A. Sezai Sarac, Jürgen Eckert
Published in: Materials Horizons, Issue 6/7, 2019, Page(s) 1481-1487, ISSN 2051-6347
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9mh00316a

Novel deformation-induced polymorphic crystallization and softening of Al-based amorphous alloys

Author(s): H.W. Bi, A. Inoue, F.F. Han, Y. Han, F.L. Kong, S.L. Zhu, E. Shalaan, F. Al-Marzouki, A.L. Greer
Published in: Acta Materialia, Issue 147, 2018, Page(s) 90-99, ISSN 1359-6454
Publisher: Elsevier BV
DOI: 10.1016/j.actamat.2018.01.016

Formation, thermal stability and mechanical properties of high-entropy (Fe0.25Co0.25Ni0.25Cr0.125Mo0.0625Nb0.0625)100‒Bx (x = 7–14) amorphous alloys

Author(s): F. Wang, A. Inoue, F.L. Kong, C.C. Zhao, J.Y. Zhang, S.L. Zhu, W.J. Botta, C.S. Kiminami, Yu P. Ivanov, A.L. Greer
Published in: Journal of Alloys and Compounds, Issue 825, 2020, Page(s) 153858, ISSN 0925-8388
Publisher: Elsevier BV
DOI: 10.1016/j.jallcom.2020.153858

Phase separation process preventing thermal embrittlement of a Zr-Cu-Fe-Al bulk metallic glass

Author(s): D.V. Louzguine-Luzgin, J. Jiang, A.I. Bazlov, V.S. Zolotorevzky, H. Mao, Yu P. Ivanov, A.L. Greer
Published in: Scripta Materialia, Issue 167, 2019, Page(s) 31-36, ISSN 1359-6462
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.scriptamat.2019.03.030

Vitrification and nanocrystallization of pure liquid Ni studied using molecular-dynamics simulation

Author(s): D. V. Louzguine-Luzgin, M. Miyama, K. Nishio, A. A. Tsarkov, A. L. Greer
Published in: The Journal of Chemical Physics, Issue 151/12, 2019, Page(s) 124502, ISSN 0021-9606
Publisher: American Institute of Physics
DOI: 10.1063/1.5119307

Formation, stability and ultrahigh strength of novel nanostructured alloys by partial crystallization of high-entropy (Fe0.25Co0.25Ni0.25Cr0.125Mo0.125)86‒89B11‒14 amorphous phase

Author(s): F. Wang, A. Inoue, F.L. Kong, S.L. Zhu, E. Shalaan, F. Al-Marzouki, W.J. Botta, C.S. Kiminami, Yu.P. Ivanov, A.L. Greer
Published in: Acta Materialia, Issue 170, 2019, Page(s) 50-61, ISSN 1359-6454
Publisher: Elsevier BV
DOI: 10.1016/j.actamat.2019.03.019

Fast-heating-induced formation of metallic-glass/crystal composites with enhanced plasticity

Author(s): Jiri Orava, Ivan Kaban, Monika Benkocka, Xiaoliang Han, Ivan Soldatov, A. Lindsay Greer
Published in: Thermochimica Acta, Issue 677, 2019, Page(s) 198-205, ISSN 0040-6031
Publisher: Elsevier BV
DOI: 10.1016/j.tca.2019.03.029

Shear-induced chemical segregation in a Fe-based bulk metallic glass at room temperature

Author(s): D. V. Louzguine-Luzgin, A. S. Trifonov, Yu. P. Ivanov, A. K. A. Lu, A. V. Lubenchenko, A. L. Greer
Published in: Scientific Reports, 2021, ISSN 2045-2322
Publisher: Nature Publishing Group

Rejuvenation through plastic deformation of a La-based metallic glass measured by fast-scanning calorimetry

Author(s): C.M. Meylan; J. Orava; A.L. Greer
Published in: Journal of Non-Crystalline Solids: X, Vol 8, Iss , Pp 100051- (2020), 2020, ISSN 2590-1591
Publisher: Elsevier
DOI: 10.1016/j.nocx.2020.100051

Direct Formation of Hard‐Magnetic Tetrataenite in Bulk Alloy Castings

Author(s): Ivanov, Yurii P; Sarac, Baran; Ketov, Sergey V; Eckert, Jürgen; Greer, A Lindsay
Published in: Advanced Science, Vol 10, Iss 1, Pp n/a-n/a (2023), 2022, ISSN 2198-3844
Publisher: Wiley VCH
DOI: 10.1002/advs.202204315

Machine learning-guided exploration and experimental assessment of unreported compositions in the quaternary Ti-Zr-Cu-Pd biocompatible metallic glass system

Author(s): Yohan Douest; Robert M. Forrest; Benoit Ter-Ovanessian; Nicolas Courtois; Franck Tancret; A. Lindsay Greer; Jérôme Chevalier; Damien Fabrègue
Published in: Acta Biomaterialia, 2024, ISSN 1742-7061
Publisher: Elsevier BV
DOI: 10.1016/j.actbio.2023.12.028

In-situ TEM study of the crystallization sequence in a gold-based metallic glass

Author(s): Yu. P. Ivanov, C. M. Meylan, N. T. Panagiotopoulos, K. Georgarakis, A. L. Greer
Published in: Acta Materialia, 2020, ISSN 1359-6454
Publisher: Elsevier BV

The effects of elastic cycling in nanoindentation of a metallic glass

Author(s): C. M. Meylan; A. L. Greer
Published in: Philosophical Magazine, 2020, ISSN 1478-6443
Publisher: Taylor and Francis
DOI: 10.1080/14786435.2020.1814494

Strain-hardening under uniaxial tension in a rejuvenated bulk metallic glass

Author(s): Zhou, WH; Panagiotopoulos, NT; Greer, AL; Li, Y
Published in: Scripta Materialia, 2022, ISSN 1359-6462
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.scriptamat.2022.114572

Novel heating- and deformation-induced phase transitions and mechanical properties for multicomponent Zr50M50, Zr50(M,Ag)50 and Zr50(M,Pd)50 (M = Fe,Co,Ni,Cu) amorphous alloys

Author(s): J. Ding, A. Inoue, F. L. Kong, S. L. Zhu, E. Shalaan, A. A. Al-Ghmadi, A. L. Greer
Published in: Journal of Materials Science and Technology, 2022, ISSN 1005-0302
Publisher: Allerton Press Inc.

Multilayer crystal-amorphous Pd-based nanosheets on Si/SiO2 with interface-controlled ion transport for efficient hydrogen storage

Author(s): Baran Sarac; Yurii P. Ivanov; Tolga Karazehir; Marlene Mühlbacher; A. Sezai Sarac; A. Lindsay Greer; Jürgen Eckert
Published in: International Journal of Hydrogen Energy, 2022, ISSN 1879-3487
Publisher: Elsevier
DOI: 10.1016/j.ijhydene.2021.12.040

Atomistic modelling of thermal-cycling rejuvenation in metallic glasses

Author(s): Shang, B; Wang, W; Greer, AL; Guan, P
Published in: Acta Materialia, 2022, ISSN 1359-6454
Publisher: Elsevier BV
DOI: 10.1016/j.actamat.2021.116952

Stimulation of shear-transformation zones in metallic glasses by cryogenic thermal cycling

Author(s): C.M. Meylan; F. Papparotto; S. Nachum; J. Orava; M. Miglierini; V. Basykh; J. Ferenc; T. Kulik; A.L. Greer
Published in: Journal of Non-Crystalline Solids, 2020, ISSN 0022-3093
Publisher: Elsevier BV
DOI: 10.1016/j.jnoncrysol.2020.120299