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New generation of nanoporous organic and hybrid aerogels for industrial applications: from the lab to pilot scale production

Risultati finali

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CFD modelling of mass transfer during sc-drying process, and concept for drying optimization on the pilot and production scale

Development of a mathematical description of the production of organic microstructured nanohybrid aerogels using tools and techniques of computational fluid dynamics (CFD). The model will then be used to asses process parameters for optimization.

Public report on final conclusions

During the funding period intermediate non-confidential results will be presented at conferences, sciences related events and in scientific journals. At the end, a documentation of final conclusions will be edited.

CA model of CO2 diffusion through the pores of the gel and modelling of aerogel structure

Cellular automata (CA) approach will be used for in-depth description of supercritical fluid drying

Report on the possible production processes of organic and hybrid aerogels and comparison with the state of the art

Report assessing the following points: -Requirements and bottlenecks for processes towards mass production -Review of the present market for synthetic polymer aerogels -Review of the state of the art of organic aerogel production with the focus on comparison monoliths/particles; potential for scale up and equipment -Choice of the common process for particle production based on and polyurethanes, polyureas, polyamides

Pubblicazioni

Production of aerogel (micro)particles: state of the art and recent advances

Autori: Pavel Gurikov, Irina Smirnova
Pubblicato in: Proceedings of the 15th European Meeting on Supercritical Fluids (EMSF), 2016
Editore: International Society for Advancement of Supercritical Fluids (ISASF)

Determination of Composition of Ethanol-CO2 Mixtures at High Pressures Using Frequency Response of Microcantilevers

Autori: Shadi Khan Baloch, Gamze Eriş, Asuman Aşıkoğlu Bozkurt, Alexandr Jonáš, Alper Kiraze, B. Erdem Alacaf, Can Erkey
Pubblicato in: Proceedings of the 15th European Meeting on Supercritical Fluids (EMSF), 2016
Editore: International Society for Advancement of Supercritical Fluids (ISASF)

Measurement of composition of mixtures at high pressures with high sensitivity using frequency response of microcantilevers (Conference Presentation)

Autori: Shadi Khan Baloch, Alper Kiraz, Alexandr Jonáš, B. Erdem Alaca, Can Erkey
Pubblicato in: Microfluidics, BioMEMS, and Medical Microsystems XVI, 2018, Pagina/e 28, ISBN 9781-510614680
Editore: SPIE
DOI: 10.1117/12.2287850

A continuous approach to the aerogel microparticle production via emulsion-gelation method

Autori: V. Baudron, P. Gurikov, I. Smirnova
Pubblicato in: Chemie Ingenieur Technik, Numero 90/9, 2018, Pagina/e 1197-1197, ISSN 0009-286X
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cite.201855144

Aerogel particle production via the emulsion-gelation method

Autori: V. Baudron, P. Gurikov, I. Smirnova
Pubblicato in: Proceedings of the 3rd International Seminar on Aerogels (2016, Sophia-Antipolis, France), 2016, ISBN 978-2-905267-93-1
Editore: Mines ParisTech

A comparison of polyurea aerogel powders from three different synthetic procedures

Autori: G.C. Anyfantis, D. Chriti, G. Raptopoulos, P. Paraskevopoulou, N. Leventis
Pubblicato in: Proceedings of the 3rd International Seminar on Aerogels (2016, Sophia-Antipolis, France), 2016, ISBN 978-2-905267-93-1
Editore: Mines TechParis

Polymeric aerogels via ring opening metathesis polymerization of urethane-norbornene star monomers

Autori: A. Kanellou, G. Anyfantis, D. Chriti, G. Raptopoulos,N. Leventis, P. Paraskevopoulou
Pubblicato in: Proceedings of the 3rd International Seminar on Aerogels (2016, Sophia-Antipolis, France), 2016, ISBN 978-2-905267-93-1
Editore: Mines ParisTech

Modeling and scale up of aerogel production processes

Autori: A.E. Lebedev, D.D. Lovskaya, N.V. Menshutina
Pubblicato in: Proceedings of the 3rd International Seminar on Aerogels (2016, Sophia-Antipolis, France), 2016, ISBN 978-2-905267-93-1
Editore: Mines ParisTech

Synthesis and structural characterization of poly(dicyclopentadiene) gels obtained with a novel ditungsten versus conventional W and Ru mononuclear catalysts

Autori: Grigorios Raptopoulos, George C. Anyfantis, Despoina Chriti, Patrina Paraskevopoulou
Pubblicato in: Inorganica Chimica Acta, 2016, ISSN 0020-1693
Editore: Elsevier BV
DOI: 10.1016/j.ica.2016.09.008

Polysaccharide-Based Aerogel Bead Production via Jet Cutting Method

Autori: Imke Preibisch, Philipp Niemeyer, Yusuf Yusufoglu, Pavel Gurikov, Barbara Milow, Irina Smirnova
Pubblicato in: Materials, Numero 11/8, 2018, Pagina/e 1287, ISSN 1996-1944
Editore: MDPI Open Access Publishing
DOI: 10.3390/ma11081287

Non-Conventional Methods for Gelation of Alginate

Autori: Pavel Gurikov, Irina Smirnova
Pubblicato in: Gels, Numero 4/1, 2018, Pagina/e 14, ISSN 2310-2861
Editore: MDPI AG
DOI: 10.3390/gels4010014

Millimeter-Size Spherical Polyurea Aerogel Beads with Narrow Size Distribution

Autori: Despoina Chriti, Grigorios Raptopoulos, Maria Papastergiou, Patrina Paraskevopoulou
Pubblicato in: Gels, Numero 4/3, 2018, Pagina/e 66, ISSN 2310-2861
Editore: MDPI AG
DOI: 10.3390/gels4030066

Determination of composition of ethanol-CO 2 mixtures at high pressures using frequency response of microcantilevers

Autori: Shadi Khan Baloch, Alexandr Jonáš, Alper Kiraz, B. Erdem Alaca, Can Erkey
Pubblicato in: The Journal of Supercritical Fluids, Numero 132, 2018, Pagina/e 65-70, ISSN 0896-8446
Editore: Elsevier BV
DOI: 10.1016/j.supflu.2017.03.027

Sensitivity of compositional measurement of high-pressure fluid mixtures using microcantilever frequency response

Autori: Shadi Khan Baloch, Alexandr Jonáš, Alper Kiraz, B. Erdem Alaca, Can Erkey
Pubblicato in: Sensors and Actuators A: Physical, Numero 278, 2018, Pagina/e 111-126, ISSN 0924-4247
Editore: Elsevier BV
DOI: 10.1016/j.sna.2018.05.025

Kinetics of Supercritical Drying of Gels

Autori: İbrahim Şahin, Yaprak Özbakır, Zeynep İnönü, Zeynep Ulker, Can Erkey
Pubblicato in: Gels, Numero 4/1, 2018, Pagina/e 3, ISSN 2310-2861
Editore: MDPI AG
DOI: 10.3390/gels4010003

Rheology of cellulose-[DBNH][CO 2 Et] solutions and shaping into aerogel beads

Autori: Lucile Druel, Philipp Niemeyer, Barbara Milow, Tatiana Budtova
Pubblicato in: Green Chemistry, Numero 20/17, 2018, Pagina/e 3993-4002, ISSN 1463-9262
Editore: Royal Society of Chemistry
DOI: 10.1039/c8gc01189c

Poly(urethane-norbornene) Aerogels via Ring Opening Metathesis Polymerization of Dendritic Urethane-Norbornene Monomers: Structure-Property Relationships as a Function of an Aliphatic Versus an Aromatic Core and the Number of Peripheral Norbornene Moieties

Autori: Aspasia Kanellou, George Anyfantis, Despoina Chriti, Grigorios Raptopoulos, Marinos Pitsikalis, Patrina Paraskevopoulou
Pubblicato in: Molecules, Numero 23/5, 2018, Pagina/e 1007, ISSN 1420-3049
Editore: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules23051007

A continuous approach to the emulsion gelation method for the production of aerogel micro-particle

Autori: Victor Baudron, Pavel Gurikov, Irina Smirnova
Pubblicato in: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Numero 566, 2019, Pagina/e 58-69, ISSN 0927-7757
Editore: Elsevier BV
DOI: 10.1016/j.colsurfa.2018.12.055

Poly(urethane-acrylate) aerogels from the isocyanurate trimer of isophorone diisocyanate

Autori: Maria Papastergiou, Despoina Chriti, Dimitrios E. Damalas, Grigorios Raptopoulos, Patrina Paraskevopoulou
Pubblicato in: The Journal of Supercritical Fluids, Numero 148, 2019, Pagina/e 42-54, ISSN 0896-8446
Editore: Elsevier BV
DOI: 10.1016/j.supflu.2019.02.020

Poly(Urethane-Acrylate) Aerogels via Radical Polymerization of Dendritic Urethane-Acrylate Monomers

Autori: Maria Papastergiou, Aspasia Kanellou, Despoina Chriti, Grigorios Raptopoulos, Patrina Paraskevopoulou
Pubblicato in: Materials, Numero 11/11, 2018, Pagina/e 2249, ISSN 1996-1944
Editore: MDPI Open Access Publishing
DOI: 10.3390/ma11112249

Review on the Production of Polysaccharide Aerogel Particles

Autori: Kathirvel Ganesan, Tatiana Budtova, Lorenz Ratke, Pavel Gurikov, Victor Baudron, Imke Preibisch, Philipp Niemeyer, Irina Smirnova, Barbara Milow
Pubblicato in: Materials, Numero 11/11, 2018, Pagina/e 2144, ISSN 1996-1944
Editore: MDPI Open Access Publishing
DOI: 10.3390/ma11112144

Investigation of kinetics of supercritical drying of alginate alcogel particles

Autori: İbrahim Şahin, Erdal Uzunlar, Can Erkey
Pubblicato in: The Journal of Supercritical Fluids, Numero 146, 2019, Pagina/e 78-88, ISSN 0896-8446
Editore: Elsevier BV
DOI: 10.1016/j.supflu.2018.12.019

Synthetic Polymer Aerogels in Particulate Form

Autori: Paraskevopoulou, Chriti, Raptopoulos, Anyfantis
Pubblicato in: Materials, Numero 12/9, 2019, Pagina/e 1543, ISSN 1996-1944
Editore: MDPI Open Access Publishing
DOI: 10.3390/ma12091543

Cellulose aero/xerogels for moisture sorption

Autori: Fernando Alvarado and Lennart Salmén
Pubblicato in: 2018
Editore: 4th International Seminar on AEROGELS

Poly(urethane-acrylate) Aerogels via Radical Polymerization of Dendritic Urethane-Acrylate Monomers with Rigid versus Flexible Cores

Autori: Patrina Paraskevopoulou, Maria Papastergiou, Despoina Chriti, Grigorios Raptopoulos
Pubblicato in: 2018
Editore: Oral presentation at 4th International Seminar on AEROGELS

Cellulose-[DBNH][CO2Et] rheological properties and aerogel beads made with JetCutting technique

Autori: L. Druel, P. Niemeyer, B. Milow and T. Budtova
Pubblicato in: 2017
Editore: 5th EPNOE International Polysaccharide Conference

Investigation of External Mass Transfer Effects in Supercritical Drying of Alcogel Particles

Autori: İbrahim Şahin, Erdal Uzunlar, Can Erkey
Pubblicato in: 2018
Editore: 4th International Seminar on AEROGELS

Design of high pressure equipment for supercritical drying

Autori: P. Tsygankov, E. Lebedev, S. Ivanov, N. Menshutina
Pubblicato in: 2018
Editore: International Smyposium on Supercritical Fluids

AEROGELEX: Enabling aerogel technology translation for care, life science, nutrition and pharmaceutical markets

Autori: Raman S.P., Pavel Gurikov and Irina Smirnova
Pubblicato in: 2018
Editore: International Smyposium on Supercritical Fluids

Cellulose aerogels shaping and properties for tailored applications

Autori: Lucile Druel, Amelie Kenkel, Philipp Niemeyer, Victor Baudron, Barbara Milow, Tatiana Budtova
Pubblicato in: 2018
Editore: Oral presentation at 4th International Seminar on AEROGELS

Novel polyvinyl alcohol aerogel for efficient removal of moisture from gaseous streams

Autori: Işık Sena Akgün, Can Erkey
Pubblicato in: 2018
Editore: International Smyposium on Supercritical Fluids

New aerogel-like materials: lightweight and mesoporous cellulose xerogels

Autori: Lucile Druel, Tatiana Budtova
Pubblicato in: 2018
Editore: 4th International Conference on Bioinspired and Biobased Chemistry

Investigation of kinetics of supercritical dryingof calcium alginate alcogol particles

Autori: İbrahim Şahin, Erdal Uzunlar, Can Erkey
Pubblicato in: 2018
Editore: International Smyposium on Supercritical Fluids

Scale-up of alginate aerogel microparticles production: development of a continuous emulsion-gelation method

Autori: Victor Baudron, Pavel Gurikov, Irina Smirnova
Pubblicato in: 2018
Editore: International Smyposium on Supercritical Fluids

Computer aided design of aerogels and materials based on it

Autori: Natalia Menshutina
Pubblicato in: 2018
Editore: International Smyposium on Supercritical Fluids

Organic aerogels as monoliths and particles: on the way from laboratory to production scale

Autori: Irina Smirnova
Pubblicato in: 2018
Editore: International Smyposium on Supercritical Fluids

Drying of aerogel particles and beads in lab and pilot scale

Autori: Sohajl Movahhed, Dirk Weinrich, Raman Subrahmanyam, Alberto Bueno, Ilka Selmer, Pavel Gurikov, Irina Smirnova
Pubblicato in: 2019
Editore: Oral presentation at PARTEC 2019 International Congress on Particle Technology

Carbon-based aerogels for adsorption of toxic gases and air decontamination

Autori: Patrina Paraskevopoulou, Despoina Chriti, Grigorios Raptopoulos, Maria Papastergiou, Barbara Milow, Benjamin Brandenburg
Pubblicato in: 2019
Editore: Oral presentation at PARTEC 2019 International Congress on Particle Technology

Aerogel particles: state of the art and recent advances

Autori: Pavel Gurikov, Victor Baudron, Imke Preibisch and Irina Smirnova
Pubblicato in: 2019
Editore: Oral presentation at PARTEC 2019 International Congress on Particle Technology

Cellulose-hybrid aero/xerogels for sorption of gas, moisture and cationic compounds

Autori: Fernando Alvarado, Lennart Salmén
Pubblicato in: 2019
Editore: Oral presentation at PARTEC 2019 International Congress on Particle Technology

Kinetics of Supercritical Drying for Production of Aerogel Particles: Effects of Process Parameters and Gel Properties

Autori: Isik Sena Akgün, İbrahim Şahin, Erdal Uzunlar, Can Erkey
Pubblicato in: 2019
Editore: Oral presentation at PARTEC 2019 International Congress on Particle Technology

Cellulose aerogels particles via emulsion technique

Autori: Lucile Druel, Amelie Kenkel, Victor Baudron, Tatiana Budtova
Pubblicato in: 2019
Editore: Oral presentation at PARTEC 2019 International Congress on Particle Technology

Chitosan-based aerogels with exceptional properties for environmental control system

Autori: Kathirvel Ganesan, Philipp D. Niemeyer, Timothy Goller and Barbara Milow
Pubblicato in: 2019
Editore: Oral presentation at PARTEC 2019 International Congress on Particle Technology

Multiscale modeling of particles supercritical drying process

Autori: Menshutina N.V., Kolnoochenko A.V., Lebedev A.E.
Pubblicato in: 2019
Editore: Oral presentation at PARTEC 2019 International Congress on Particle Technology

Synthesis of Polyurea Aerogel Powders with Three Different Procedures

Autori: D. Chriti, G. Raptopoulos, G. Anyfantis, P. Paraskevopoulou, N. Leventis
Pubblicato in: 2016
Editore: Athens International Catalysis Symposium (AICS) 2016

Polymeric Aerogels via Ring Opening Metathesis Polymerization of Aliphatic and Aromatic Urethane-Norbornene Star Monomers

Autori: A. Kanellou, G. Anyfantis, D. Chriti, G. Raptopoulos, N. Leventis, P. Paraskevopoulou
Pubblicato in: 2016
Editore: Athens International Catalysis Symposium (AICS) 2016

Synthesis and Properties of high-cis Polydicyclopentadiene Gels

Autori: G. Raptopoulos, D. Chriti, G. Anyfantis, P. Paraskevopoulou
Pubblicato in: 2016
Editore: Athens International Catalysis Symposium (AICS) 2016

Hansen Solubility Parameters and Potential Applications of Poly(dicyclopentadiene) Gels

Autori: G. Raptopoulos, D. Chriti, G. Anyfantis, P. Paraskevopoulou
Pubblicato in: 2016
Editore: Athens International Catalysis Symposium (AICS) 2016

Modelling of the extraction processes for aerogel production

Autori: Irina Smirnova, Alberto Bueno Morales, Ilka Selmer, Raman Subrahmanyam and Pavel Gurikov
Pubblicato in: 2017
Editore: Materials Research Society

Polysaccharide Based Aerogels as Sustainable Absorbing Materials

Autori: Barbara Milow, Philipp Niemeyer and Kathirvel Ganesan
Pubblicato in: 2017
Editore: Materials Researc Society

Catalytic Polymerization of Olefins and Cycloolefins with Transition Metal Complexes

Autori: Grigorios Raptopoulos
Pubblicato in: 2016
Editore: National and Kapodistrian University of Athen

Synthesis of urethane-norbornene star monomers. Synthesis of aerogels via ring opening metathesis polymerization of those monomers

Autori: A. Kanellou
Pubblicato in: 2017
Editore: National and Kapodistrian University of Athens

Processes of obtaining organic aerogels based on sodium alginate and compositions on their basis

Autori: D.D. Lovskaya
Pubblicato in: 2017
Editore: Mendeleev University of Chemical Technology of Russia

Effect of ZnO concentration, drying method and coagulation bath on the properties cellulose materials

Autori: Omar Cardenas
Pubblicato in: 2017
Editore: Mines ParisTech

Study of the chemical reactivity of W complexes in ROMP of urethane-norbornene star-shaped monomers

Autori: S. Miliakou
Pubblicato in: 2017
Editore: National and Kapodistrian University of Athens

Processes of obtaining aerogels with impregnated carbon nanotubes in high-pressure apparatuses and its intensification

Autori: Pavel Tsygankov
Pubblicato in: 2018
Editore: Mendeleev University of Chemical Technology of Russia

Simulation of the structure and properties of the functional material - aerogel with embedded carbon nanotubes

Autori: Andrey Tyrtishnikov
Pubblicato in: 2018
Editore: Mendeleev University of Chemical Technology of Russia

Modeling of the structure, properties and processes of obtaining silica - resortsinol-formaldehyde and silica-carbon aerogels

Autori: Igor Lebedev
Pubblicato in: 2018
Editore: Mendeleev University of Chemical Technology of Russia

Production of cellulose aerogel beads using emulsions

Autori: Amelie Kenkel
Pubblicato in: 2017
Editore: Technische Universität Hamburg

Microcantilever Based Sensor for Characterization of Ethanol-CO2 Fluid Mixtures at High Pressures

Autori: Shadi Khan Baloch
Pubblicato in: 2018
Editore: Koc University

Cellulose based aerogels: properties and shaping as beads

Autori: L. Druel
Pubblicato in: 2019
Editore: University of Paris

Modelling of Aerogels Structures Using Intelligent System «AeroGen Structure»

Autori: Igor Mitrofanov, Irina Malysheva, Andrey Kolnoochenko, Natalia Menshutina
Pubblicato in: Computer Aided Chemical Engineering, Numero 40, 2017, Pagina/e 469-474
Editore: Elsevier
DOI: 10.1016/b978-0-444-63965-3.50080-5

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