Synthesis of methanol from captured carbon dioxide using surplus electricity

Informazioni relative al progetto

MefCO2

ID dell’accordo di sovvenzione: 637016

DOI 10.3030/637016

Progetto chiuso

Data della firma CE 7 Novembre 2014

Data di avvio 1 Dicembre 2014

Data di completamento 30 Giugno 2019

Finanziato da

• INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced manufacturing and processing

Costo totale € 11 068 323,75

Contributo UE € 8 622 292,60

Coordinato da

I-DEALS INNOVATION & TECHNOLOGY VENTURING SERVICES SL
Spain

Risultati finali

Demonstrators, pilots, prototypes (4)

Real-scale reactor model
Optimal process operation and conditions, and catalyst synthesis scale-up
Operational laboratory-scale reaction models

Operational laboratory-scale reaction models.

Operational laboratory-scale reactors

Operational laboratory-scale reactors.

Pubblicazioni

Peer reviewed articles (8)

Unravelling the mechanisms of CO 2 hydrogenation to methanol on Cu-based catalysts using first-principles multiscale modelling and experiments

Autori: Matej Huš, Drejc Kopač, Neja Strah Štefančič, Damjan Lašič Jurković, Venkata D. B. C. Dasireddy, Blaž Likozar
Pubblicato in: Catalysis Science & Technology, Numero 7/24, 2017, Pagina/e 5900-5913, ISSN 2044-4753
Editore: Royal Society of Chemistry
DOI: 10.1039/C7CY01659J

Kinetic Monte Carlo Simulations of Methanol Synthesis from Carbon Dioxide and Hydrogen on Cu(111) Catalysts: Statistical Uncertainty Study

Autori: Drejc Kopač, Matej Huš, Mitja Ogrizek, Blaž Likozar
Pubblicato in: The Journal of Physical Chemistry C, Numero 121/33, 2017, Pagina/e 17941-17949, ISSN 1932-7447
Editore: American Chemical Society
DOI: 10.1021/acs.jpcc.7b04985

Mechanism, kinetics and thermodynamics of carbon dioxide hydrogenation to methanol on Cu/ZnAl 2 O 4 spinel-type heterogeneous catalysts

Autori: Matej Huš, Venkata D.B.C. Dasireddy, Neja Strah Štefančič, Blaž Likozar
Pubblicato in: Applied Catalysis B: Environmental, Numero 207, 2017, Pagina/e 267-278, ISSN 0926-3373
Editore: Elsevier BV
DOI: 10.1016/j.apcatb.2017.01.077

The CO 2 economy: Review of CO 2 capture and reuse technologies

Autori: Efthymia Ioanna Koytsoumpa, Christian Bergins, Emmanouil Kakaras
Pubblicato in: The Journal of Supercritical Fluids, Numero 132, 2018, Pagina/e 3-16, ISSN 0896-8446
Editore: Elsevier BV
DOI: 10.1016/j.supflu.2017.07.029

Solvent Free Synthesis of PdZn/TiO2 Catalysts for the Hydrogenation of CO2 to Methanol

Autori: Hasliza Bahruji, Jonathan Ruiz Esquius, Michael Bowker, Graham Hutchings, Robert D. Armstrong, Wilm Jones
Pubblicato in: Topics in Catalysis, Numero 61/3-4, 2018, Pagina/e 144-153, ISSN 1022-5528
Editore: Baltzer Science Publishers B.V.
DOI: 10.1007/s11244-018-0885-6

The Effects of Secondary Oxides on Copper-Based Catalysts for Green Methanol Synthesis

Autori: James S. Hayward, Paul J. Smith, Simon A. Kondrat, Michael Bowker, Graham J. Hutchings
Pubblicato in: ChemCatChem, Numero 9/9, 2017, Pagina/e 1655-1662, ISSN 1867-3880
Editore: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201601692

PdZn catalysts for CO 2 hydrogenation to methanol using chemical vapour impregnation (CVI)

Autori: H. Bahruji, M. Bowker, W. Jones, J. Hayward, J. Ruiz Esquius, D. J. Morgan, G. J. Hutchings
Pubblicato in: Faraday Discussions, Numero 197, 2017, Pagina/e 309-324, ISSN 1359-6640
Editore: Royal Society of Chemistry
DOI: 10.1039/C6FD00189K

The Challenge of Energy Storage in Europe: Focus on Power to Fuel

Autori: Efthymia-Ioanna Koytsoumpa, Christian Bergins, Torsten Buddenberg, Song Wu, Ómar Sigurbjörnsson, K. C. Tran, Emmanouil Kakaras
Pubblicato in: Journal of Energy Resources Technology, Numero 138/4, 2016, Pagina/e 042002, ISSN 0195-0738
Editore: ASME
DOI: 10.1115/1.4032544

Non-peer reviewed articles (12)

Catalytic Hydrogenation of Carbon Dioxide to Methanol: Synergistic Effect of Bifunctional Cu/Perovskite Catalysts

Autori: Matej Huš, Drejc Kopač, Blaž Likozar
Pubblicato in: ACS Catalysis, Numero 9/1, 2018, Pagina/e 105-116, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.8b03810

Correlation between synthesis pH, structure and Cu/MgO/Al2O3 heterogeneous catalyst activity and selectivity in CO2 hydrogenation to methanol

Autori: Venkata D.B.C. Dasireddy, Strah Štefančič Neja, Likozar Blaž
Pubblicato in: Journal of CO2 Utilization, Numero 28, 2018, Pagina/e 189-199, ISSN 2212-9820
Editore: Elsevier BV
DOI: 10.1016/j.jcou.2018.09.002

The role of copper oxidation state in Cu/ZnO/Al2O3 catalysts in CO2 hydrogenation and methanol productivity

Autori: Venkata D.B.C. Dasireddy, Blaž Likozar
Pubblicato in: Renewable Energy, Numero 140, 2019, Pagina/e 452-460, ISSN 0960-1481
Editore: Pergamon Press Ltd.
DOI: 10.1016/j.renene.2019.03.073

Comparison of computational fluid dynamics (CFD) and pressure drop correlations in laminar flow regime for packed bed reactors and columns

Autori: Andraž Pavlišič, Rok Ceglar, Andrej Pohar, Blaž Likozar
Pubblicato in: Powder Technology, Numero 328, 2018, Pagina/e 130-139, ISSN 0032-5910
Editore: Elsevier BV
DOI: 10.1016/j.powtec.2018.01.029

Effect of alkaline earth metal oxide (MO) Cu/MO/Al2O3 catalysts on methanol synthesis activity and selectivity via CO2 reduction

Autori: Venkata D.B.C. Dasireddy, Neja Strah Štefančič, Matej Huš, Blaž Likozar
Pubblicato in: Fuel, Numero 233, 2018, Pagina/e 103-112, ISSN 0016-2361
Editore: Elsevier BV
DOI: 10.1016/j.fuel.2018.06.046

Thermodynamic and economic analysis of a plant for the CO 2 hydrogenation for methanol production

Autori: Daria Bellotti, Matthias Dierks, Florian Moellenbruck, Loredana Magistri, Klaus Görner, Gerd Oeljeklaus
Pubblicato in: E3S Web of Conferences, Numero 113, 2019, Pagina/e 01013, ISSN 2267-1242
Editore: e3conferences
DOI: 10.1051/e3sconf/201911301013

RSM approach for stochastic sensitivity analysis of the economic sustainability of a methanol production plant using renewable energy sources

Autori: Daria Bellotti, Lucia Cassettari, Marco Mosca, Loredana Magistri
Pubblicato in: Journal of Cleaner Production, Numero 240, 2019, Pagina/e 117947, ISSN 0959-6526
Editore: Elsevier BV
DOI: 10.1016/j.jclepro.2019.117947

Techno-economic analysis for the integration of a power to fuel system with a CCS coal power plant

Autori: D. Bellotti, A. Sorce, M. Rivarolo, L. Magistri
Pubblicato in: Journal of CO2 Utilization, Numero 33, 2019, Pagina/e 262-272, ISSN 2212-9820
Editore: Elsevier BV
DOI: 10.1016/j.jcou.2019.05.019

Feasibility study of methanol production plant from hydrogen and captured carbon dioxide

Autori: D. Bellotti, M. Rivarolo, L. Magistri, A.F. Massardo
Pubblicato in: Journal of CO2 Utilization, Numero 21, 2017, Pagina/e 132-138, ISSN 2212-9820
Editore: Elsevier BV
DOI: 10.1016/j.jcou.2017.07.001

Economic feasibility of methanol synthesis as a method for CO2 reduction and energy storage

Autori: D. Bellotti, M. Rivarolo, L. Magistri
Pubblicato in: Energy Procedia, Numero 158, 2019, Pagina/e 4721-4728, ISSN 1876-6102
Editore: Science Direct
DOI: 10.1016/j.egypro.2019.01.730

Feasibility study of methanol production from different renewable sources and thermo-economic analysis

Autori: M. Rivarolo, D. Bellotti, L. Magistri, A.F. Massardo
Pubblicato in: International Journal of Hydrogen Energy, Numero 41/4, 2016, Pagina/e 2105-2116, ISSN 0360-3199
Editore: Pergamon Press Ltd.
DOI: 10.1016/j.ijhydene.2015.12.128

Energy storage and grid for electricity, gas, fuel and heat - a system-wide approach

Autori: Dr. W.A. Benesch, Prof. E. Kakaras
Pubblicato in: VGB Powertech, 2016
Editore: VGB Powertech

Conference proceedings (1)

Power to Methanol Solutions for Flexible and Sustainable Operations in Power and Process Industries

Autori: C. Bergins, K.-C. Tran, E.-I. Koytsoumpa, E. Kakaras, T. Buddenberg, Ó. Sigurbjörnsson
Pubblicato in: 2015
Editore: POWER-GEN Europe 2015