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Hierarchical self-assembly of electroactive supramolecular systems on pRe-patterned surfaces: multifunctional architectures for organic FETs

Objectif

HESPERUS aims at enabling cross-disciplinary training and research at the interface between Electrical Engineering, Supramolecular Chemistry, Materials- and Nano-Science and Physics. The overall goal of HESPERUS is to generate new scientific and technological knowledge by combining supramolecularly engineered nanostructures (SENs), mostly based on organic semiconductors, with tailor-made interfaces to textured solid substrates and electrodes, for fabricating prototypes of two-terminal devices (supramolecular wires) and three-terminal devices (field-effect transistors). The training and research objectives of HESPERUS are: 1. Surface texturing: derivatization of electrically conductive solid substrates and metallic nanostructures to achieve a full control over the surface work-function, wettability and adhesion, thus ultimately to be able to tune the self-assembly of electroactive molecules at surfaces into pre-programmed supramolecular assemblies. 2. Hierarchical self-organization on textured surface of multifunctional SENs based on electrically/optically active functionalized carbon-based (I) 2D nano-objects such as n- and p-type discotics (perylenediimide and hexabenzocoronene derivatives) and (II) polymeric multichromophoric architectures at surfaces on the functionalized substrates. 3. Nanochemistry and nanoprobes: Scanning probes (AFM, STM, KPFM, C-AFM) quantitative time and space resolved characterization of various physico chemical properties of SENs, in particular correlation between structural and electronic properties. 4. Fabrication of supramolecular wires and transistors: Measurement of charge mobility in SENs two- and three-terminal devices varying systematically the wire’s (1) chemical composition, (2) conformation, (3) length and (4) doping.

Champ scientifique

CORDIS classe les projets avec EuroSciVoc, une taxonomie multilingue des domaines scientifiques, grâce à un processus semi-automatique basé sur des techniques TLN.

Appel à propositions

FP7-PEOPLE-2007-2-1-IEF
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Coordinateur

CONSIGLIO NAZIONALE DELLE RICERCHE
Contribution de l’UE
€ 162 985,98
Adresse
PIAZZALE ALDO MORO 7
00185 Roma
Italie

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Région
Centro (IT) Lazio Roma
Type d’activité
Research Organisations
Contact administratif
Roberto Zamboni (Dr.)
Liens
Coût total
Aucune donnée