Small Molecule Activation by Main-Group Compounds

Project Information

SMAC-MC

Grant agreement ID: 772510

DOI 10.3030/772510

Project closed

EC signature date 17 January 2018

Start date 1 July 2018

End date 31 December 2023

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 424 190,00

EU contribution € 1 424 190,00

Coordinated by

JYVASKYLAN YLIOPISTO
Finland

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Thesis and dissertations (1)

Main Group Diradicals and their Reactivity with Small Molecules, B.Sc. Thesis (Pääryhmien diradikaaliyhdisteistä ja niiden reaktiivisuudesta pienten molekyylien kanssa, LuK tutkielma)

Author(s): Iida Ulaska
Published in: 2020
Publisher: Department of Chemistry, University of Jyväskylä

Peer reviewed articles (10)

Molecular Complexes Featuring Unsupported Dispersion-Enhanced Aluminum–Copper and Gallium–Copper Bonds

Author(s): Kristian L. Mears, Cary R. Stennett, Elina K. Taskinen, Caroline E. Knapp, Claire J. Carmalt, Heikki M. Tuononen, Philip P. Power
Published in: Journal of the American Chemical Society, Issue 142/47, 2020, Page(s) 19874-19878, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c10099

Low-Valent Germanylidene Anions: Efficient Single-Site Nucleophiles for Activation of Small Molecules.

Author(s): Chris Gendy; J. Mikko Rautiainen; Aaron Mailman; Heikki M. Tuononen
Published in: Chemistry - A European Journal, Issue 27/58, 2022, Page(s) 14405-14409, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202102804

The Monomeric Alanediyl : AlAr i Pr8 (Ar i Pr8 = C 6 H-2,6-(C 6 H 2 -2,4,6-Pr i

Author(s): Joshua D. Queen, Annika Lehmann, James C. Fettinger, Heikki M. Tuononen, Philip P. Power
Published in: Journal of the American Chemical Society, Issue 142/49, 2020, Page(s) 20554-20559, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c10222

Bis[cyclic (alkyl)(amino)carbene] isomers: Stable <i>trans</i>-bis(CAAC) <i>versus</i> facile olefin formation for <i>cis</i>-bis(CAAC)

Author(s): Braulio M. Puerta Lombardi; Ethan R. Pezoulas; Roope A. Suvinen; Alexander Harrison; Zachary S. Dubrawski; Benjamin S. Gelfand; Heikki M. Tuononen; Roland Roesler
Published in: Chemical Communications, Issue 58/45, 2022, Page(s) 6482-6485, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc01476a

Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation

Author(s): Joschua Helmer; Olli J. Pakkanen; Chris Gendy; Alexander Hepp; Heikki M. Tuononen; Felicitas Lips
Published in: Chemical Communications, Issue 58/21, 2022, Page(s) 3549-3552, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc00298a

A Monomeric Aluminum Imide (Iminoalane) with Al–N Triple-Bonding: Bonding Analysis and Dispersion Energy Stabilization

Author(s): Joshua D. Queen, Sini Irvankoski, James C. Fettinger, Heikki M. Tuononen, Philip P. Power
Published in: Journal of the American Chemical Society, Issue 143/17, 2021, Page(s) 6351-6356, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c02463

Side‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel

Author(s): Braulio Michele Puerta Lombardi, Chris Gendy, Benjamin S. Gelfand, Guy M. Bernard, Roderick E. Wasylishen, Heikki M. Tuononen, Roland Roesler
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202011301

An isolable, chelating bis[cyclic (alkyl)(amino)carbene] stabilizes a strongly bent, dicoordinate Ni(0) complex

Author(s): Braulio M. Puerta Lombardi, Morgan R. Faas, Daniel West, Roope A. Suvinen, Heikki M. Tuononen, Roland Roesler
Published in: Nature Communications, Issue 15/3417, 2024, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-024-47036-7

Hydrobismuthation: Insertion of Unsaturated Hydrocarbons into the Heaviest Main Group Element Bond to Hydrogen

Author(s): Kristian L. Mears, Gia-Ann Nguyen, Bronson Ruiz, Annika Lehmann, Jonah Nelson, James C. Fettinger, Heikki M. Tuononen, Power P. Power
Published in: Journal of the American Chemical Society, Issue 146/1, 2024, Page(s) 19-23, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c06535

Haptotropism in a Nickel Complex with a Neutral, π‐Bridging <i>cyclo</i> ‐P ₄ Ligand Analogous to Cyclobutadiene

Author(s): Chris Gendy; Juuso Valjus; Heikki M. Tuononen; Roland Roesler
Published in: Angewandte Chemie International Edition, Issue 61/18, 2022, Page(s) e202115692, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202115692